The corrosion and dissolution of a new magnesium-lithium (Mg-Li) alloy was studied using an electrochemical flow cell coupled with inductively coupled plasma-mass spectroscopy (ICP-MS) allowing real-time spectroelectrochemical analysis. The alloy studied is a corrosion resistant Mg-33at. % Li alloy, which possesses a body centered cubic matrix and a homogenous nanostructure. A detailed investigation of the dissolution kinetics of this alloy is important for understanding the origins of its apparently high corrosion resistance. Whilst the alloy composition ratio of Mg: Li is similar to 2, it was revealed that the dissolution ratio of metallic Mg: Li in 0.01 M NaCl was similar to 3.4 via downstream detection of ions. The deficiency of Li detected in the downstream electrolyte via ICP-MS was attributed to the development of a persistent Li-rich surface film that forms dynamically in the open circuit condition and for applied potentials below similar to-1050 mV(Ag/AgCl). For potentials positive to similar to-1050 mV(Ag/AgCl), significant Li ion detection in solution was observed, commensurate with the alloy compositional ratio. (C) 2016 The Electrochemical Society. All rights reserved.