Proton magnetic resonance (MR) imaging at 300 MHz was used to characterise the dewatering of Pinus radiata sapwood. The sapwood was immersed in CO2 that was cycled at temperatures greater than 31 degrees C between gas (0.1-6 MPa) and supercritical fluid (15-20 MPa) phase. A combination of FLASH and RARE pulse sequences were used to highlight differences in T-2*(H) and T-2(H) relaxation. It was observed that CO2 entered into the green sapwood via air or water vapour-filled cells in the latewood and then diffused into earlywood cells adjacent to the pith side of the latewood bands. The dissolved CO2 reduced the surface tension of water which facilitated the expulsion of sap. As the pressure was released, and CO2 bubbles formed and expanded, the sap flowed tangentially towards the surfaces. This accounted, in part, for the observed independence of sample size on the supercritical CO2 dewatering process. (C) 2016 Elsevier B.V. All rights reserved.