The fires and explosions caused by flammable hydrocarbon air mixtures are a major safety concern in the chemical and processing industries. The thermo-physical and chemical properties of the flammable fuels in a hybrid form appear to have a significant impact on the combustion process. This usually occurs due to substantial changes in the flammability concentration regimes. The aim of this study is to investigate the fire and explosive properties of hybrid fuels in the chemical and process industries. In addition, it examines the impact of the ignition energy and vessel geometry on the magnitude of the pressure rise and flame propagation velocity. The experimental work was conducted on a cylindrically shaped explosion chamber constructed as part of this study at The University of Newcastle, Australia. The chamber was made of mild steel and was 30 m in length and 0.5 in diameter. It included a series of high resolution pressure transducers, a pyrometer, as well as a high speed video camera. Methane and coal dust were used as fuels and chemical igniters with a known energy were used to ignite the fuels. The results obtained from this study showed that both the ignition energy and the diluted combustible fuel dust have significant impacts on the Over Pressure Rise (OPR) in an explosion chamber. The significant findings included that the OPR doubled when 30 g m(-3) of coal dust was added to a 6% methane/air mixture, and it increased by 60% when 10 kJ was used instead of a 1 kJ ignition source. The initial ignition energy was observed to considerably enhance the speed of both the pressure wave and the flame front, where the pressure wave speed doubled when using a 5 kJ instead of a 1 kJ ignition source. However, the pressure wave speed increased by five times when a 10 kJ was used instead of a 1 kJ ignition source. Additionally, the maximum flame front velocity observed for the ignition source with 5 kJ energy was twice the flame front velocity for the I kJ ignition source. Finally, it was observed that the time needed for the initial methane ignition was reduced by about 50% when using a 10 kJ instead of a 1 kJ ignition source. (C) 2016 Elsevier Ltd. All rights reserved.