Journal of Electroanalytical Chemistry, Vol.689, 291-296, 2013
Electrochemical and electrochromic properties of two novel polymers containing carbazole and phenyl-methanone units
Two new electrochromic materials consisting of carbazole and phenyl-methanone units, 4-(9H-carbazol-9-yl)-phenyl-methanone (CPM) and 4-(3,6-di(thiophen-2-yl)-9H-carbazol-9-yl)-phenyl-methanone (TCPM), were synthesized and characterized. Both the compounds show well-defined oxidation and reduction processes. Spectroelectrochemical analysis reveals that their polymers display reasonable optical contrast (25%,41%) and fast switching time (3 s,2 s). Cyclic voltammogram study confirms that the polymer with the existence of thiophene units is more stable in electrochemical environment. (C) 2012 Elsevier B.V. All rights reserved.