화학공학소재연구정보센터
Journal of Electroanalytical Chemistry, Vol.739, 211-217, 2015
Corrosion protection afforded by praseodymium conversion film on Mg alloy AZNd in simulated biological fluid studied by scanning electrochemical microscopy
Surface passivation of AZNd Mg alloy with Pr(NO3)(3) is studied using scanning electrochemical microscopy (SECM) in surface generation/tip collection (SG/TC) and AC modes. Corrosion protection afforded by the Pr treatment and the degradation mechanism in a simulated biological environment was examined on a local scale and compared with non-treated AZNd. SG/TC mode results revealed a drastic decrease in H-2 evolution due to the Pr treatment. Mapping the local insulating characteristics using AC SECM showed higher conductivity of the surface where H-2 evolution was most favorable. (C) 2014 Elsevier B.V. All rights reserved.