Journal of Membrane Science, Vol.147, No.1, 59-71, 1998
Modelling of vapour sorption in polar materials : Comparison of Flory-Huggins and related models with the ENSIC mechanistic approach
This work focuses on the analysis of organic vapour sorption in polymer systems strongly deviating from ideality. The sorption of three different types of organics (i.e. alcohol, ether, ester) in polyurethaneimide block copolymers has been investigated using a microgravimetric technique over the entire activity range. For all the polyurethaneimides, sorption increases in the following order : ETBE
Keywords:DENSE SILICONE MEMBRANES;PREFERENTIAL SORPTION;ORGANIC-SOLVENTS;PERVAPORATION;POLYMER;POLYSTYRENE;PREDICTION;SEPARATION;SOLUBILITIES;EQUILIBRIA