Applied Surface Science, Vol.366, 245-253, 2016
The effect of yttrium addition on oxidation of a sputtered nanocrystalline coating with moderate amount of tantalum in composition
The effect of yttrium addition on isothermal oxidation at 1050 degrees C of a sputtered nanocrystalline coating with moderate amount of tantalum in composition was investigated. Results indicate that yttrium addition delays transformation of metastable theta-Al2O3 to equilibrium alpha-Al2O3 grown on the nanocrystalline coatings. It prevents scale rumpling and promotes the formation of oxide pegs at interface between the oxide scale and the underlying coating. Besides, yttrium prefers to segregate at grain boundaries of the nanocrystalline coating and retards the outward transportation of tantalum from coating to oxide scale, thus reducing the excessive oxidation of tantalum. (C) 2016 Elsevier B.V. All rights reserved.
Keywords:Single-crystal superalloys;Nanocrystalline coating;High-temperature oxidation;Reactive element effect