UV 경화 코팅의 광중합에 대한 라만분광학 분석

Fengguo Liu; Ying Wang; Xiangxin Xue; He Yang

Polymer(Korea), Vol.40, No.3, 390-396, May, 2016

DOI10.7317/pk.2016.40.3.390 Export Citation

UV 경화 코팅의 광중합에 대한 라만분광학 분석

Photopolymerization of UV Curable Coatings Monitored by Raman Spectroscopy

Fengguo Liu^{1, 2}, Ying Wang¹, Xiangxin Xue^{1, 2, †}, and He Yang^{1, 2}

¹School of Metallurgy, Northeastern University, Shenyang 110819, China
²Liaoning Key Laboratory of Metallurgical Resource Recycling Science, Northeastern University, Shenyang 110819, China

E-mail:

Photopolymerization process of UV curable coatings based on epoxy acrylate/tripropylene glycol diacrylate was monitored by Raman spectroscopy. The consumption of C=C double bond in coatings was observed under UV irradiation. Quantitative analysis of curing degree versus UV irradiation time was investigated by fitting Raman spectra. The results indicated that the initiation efficiency of cleavage type photoinitiators and Irgacure 184 are superior to that of hydrogen-abstraction type photoinitiator. High photoinitiator concentration is beneficial for achieving fast photopolymerization rate and high final conversion. However, when the concentration of photoinitiator exceeds a certain value, the polymerization rate and final conversion will not increase evidently because of initiation efficiency and free volume effect.

Keywords:Raman spectroscopy;UV curable coating;phptopolymerization;kinetics

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[Referenced By]

[1] Decker C, Macromol. Rapid Commun., 23(18), 1067 (2002)

[2] Yagci Y, Jockusch S, Turro NJ, Macromolecules, 43(15), 6245 (2010)

[3] Zhang X, Yang J, Zeng Z, Huang L, Chen Y, Wang H, Polym. Int., 55, 466 (2006)

[4] Cho JD, Hong JW, J. Appl. Polym. Sci., 93(3), 1473 (2004)

[5] Aerykssen JH, Khudyakov IV, Ind. Eng. Chem. Res., 50(3), 1523 (2011)

[6] Chemtob A, Versace DL, Belon C, Croutxe-Barghorn C, Rigolet S, Macromolecules, 41(20), 7390 (2008)

[7] Yu YY, Chien WC, Chen SY, Mater. Des., 31, 2061 (2010)

[8] Zhang S, Chen Z, Guo M, Zhao J, Liu X, RSC Adv., 4, 30938 (2014)

[9] Wang Y, Liu F, Xue X, Prog. Org. Coat., 76, 863 (2013)

[10] Yu B, Wang X, Xing WY, Yang HY, Song L, Hu Y, Ind. Eng. Chem. Res., 51(45), 14629 (2012)

[11] Jancvicva V, Mikula M, Havlinova B, Jakubikova Z, Prog. Org. Coat., 76, 432 (2013)

[12] Li FS, Zhou SX, You B, Wu LM, J. Appl. Polym. Sci., 99(4), 1429 (2006)

[13] De Paz H, Chemtob A, Croutxe-Barghorn C, Le Nouen D, Rigolet S, J. Phys. Chem. B, 116(17), 5260 (2012)

[14] Decker C, Moussa K, Macromolecules, 22, 4455 (1989)

[15] Hwang HD, Park CH, Moon JI, Kim HJ, Masubuchi T, Prog. Org. Coat., 72, 663 (2011)

[16] Corcione CE, Frigione M, Maffezzoli A, Malucelli G, Eur. Polym. J., 44, 2010 (2008)

[17] Scott TF, Cook WD, Forsythe JS, Polymer, 43(22), 5839 (2002)

[18] Scott TF, Cook WD, Forsythe JS, Polymer, 44(3), 671 (2003)

[19] Corcione CE, Malucelli G, Frigione M, Maffezzoli A, Polym. Test, 28, 157 (2009)

[20] Nichols ME, Seubert CM, Weber WH, Gerlock JL, Prog. Org. Coat., 43, 226 (2001)

[21] Lampakis D, Manoudis PN, Karapanagiotis I, Prog. Org. Coat., 76, 488 (2013)

[22] Jin J, Lim H, Park H, Kim SS, Song K, Tashiro K, Polym. Korea, 27(6), 603 (2003)

[23] Schrof W, Beck E, Koniger R, Reich W, Schwalm R, Prog. Org. Coat., 35, 197 (1999)

[24] Posset U, Gigant K, Schottner G, Baia L, Popp J, Opt. Mater., 26, 173 (2004)

[25] Courtecuisse F, Cerezo J, Croutxe-Barghorn C, Dietlin C, Allonas X, J. Polym. Sci. A: Polym. Chem., 51(3), 635 (2013)

[26] Asmussen S, Schroeder W, dell’Erba I, Vallo C, Polym. Test, 32, 1283 (2013)

[27] Cai Y, Jessop JLP, Polymer, 47(19), 6560 (2006)

[28] Wertheim GK, Butler MA, West KW, Buchanan DNE, Rev. Sci. Instrum., 45, 1369 (1974)

[29] Tai FC, Lee SC, Chen J, Wei C, Chang SH, J. Raman Spectrosc., 40, 1055 (2009)

[30] Bradley M, Thermo Fisher Scientific, U.S.A., Application Note:50733 (2007).

[31] Lecamp L, Youssef B, Bunel C, Lebaudy P, Polymer, 40(6), 1403 (1999)

[32] Lecamp L, Youssef B, Bunel C, Lebaudy P, Polymer, 38(25), 6089 (1997)

[33] Jiang XS, Xu HJ, Yin H, Polymer, 45(1), 133 (2004)

[34] Rudnick J, Taylor PL, Litt M, Hopfinger AJ, J. Polym. Sci. B: Polym. Phys., 17, 311 (1979)

[35] Frisch HL, Klempner D, Kwei TK, Macromolecules, 4, 237 (2002)