Korean Journal of Chemical Engineering, Vol.33, No.6, 1883-1888, June, 2016
A novel CCU approach of CO2 by the system 1,2-ethylenediamine+1,2-ethylene glycol
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As a new, effective CO2 fixation system, 1,2-ethylenediamine and 1,2-ethylene glycol (EDA+EG) can efficiently activate CO2 and directly convert it into a novel CO2-storage material (CO2SM) with 46.3% yield. The aqueous CO2SM solution can react with Ca(OH)2-saturated limpid solution to generate morphology-controllable CaCO3 microparticles with additional CO2 bubbling and Ca(OH)2. Additionally, the aqueous EDA+EG solution could be recycled multiple times without significant loss of CO2 capturing and releasing capabilities.
Keywords:CO2 Capture;Storage and Utilization;CO2-storage Material;Absorption-desorption Cycle;CaCO3 Microparticle
- Mores P, Scenna N, Mussati S, Energy, 45(1), 1042 (2012)
- Han K, Ahn CK, Lee MS, Rhee CH, Kim JY, Chun HD, Int. J. Greenh. Gas Con., 14, 270 (2013)
- Li FF, Yang ZH, Zeng R, Yang G, Chang X, Yan JB, Hou YL, Ind. Eng. Chem. Res., 50(10), 6496 (2011)
- Zaman M, Lee JH, Korean J. Chem. Eng., 30(8), 1497 (2013)
- Ma SC, Chen GD, Han TT, Zhu SJ, Yang J, Int. J. Greenh. Gas Con., 37, 249 (2015)
- Carapellucci R, Giordano L, Vaccarelli M, Energy, 85, 594 (2015)
- Goeppert A, Czaun M, Prakash GKS, Olah GA, Energy Environ. Sci., 5, 7833 (2012)
- Hunt AJ, Sin EHK, Marriott R, Clark JH, ChemSusChem., 3, 306 (2010)
- Barbarossa V, Barzagli F, Mani F, Lai S, Stoppioni P, Vanga G, RSC Adv., 3, 12349 (2013)
- Sathre R, Chester M, Cain J, Masanet E, Energy, 37(1), 540 (2012)
- Li HL, Ditaranto M, Berstad D, Energy, 36(2), 1124 (2011)
- Jin HG, Gao L, Han W, Hong H, Energy, 35(11), 4499 (2010)
- Sculley JP, Zhou HC, Angew. Chem.-Int. Edit., 51, 12660 (2012)
- Bonenfant D, Mimeault M, Hausler R, Ind. Eng. Chem. Res., 42(14), 3179 (2003)
- Camper D, Bara JE, Gin DL, Noble RD, Ind. Eng. Chem. Res., 47(21), 8496 (2008)
- Seo H, Min DY, Kang NY, Choi WC, Park S, Park YK, Lee DK, Korean J. Chem. Eng., 32(1), 51 (2015)
- Wang T, Jens K, Int. J. Greenh. Gas Con., 37, 354 (2015)
- Wang JY, Huang L, Yang RY, Zhang Z, Wu JW, Gao YS, Wang Q, Hare DO, Zhong ZY, Energy Environ. Sci., 7, 3478 (2014)
- Ho MT, Allinson GW, Wiley DE, Ind. Eng. Chem. Res., 47(5), 1562 (2008)
- Huang J, Zou J, Ho WSW, Ind. Eng. Chem. Res., 47(4), 1261 (2008)
- Heldebrant DJ, Koech PK, Ang TM, Chen L, Rainbolt JE, Yonkera CR, Jessop PG, Green Chem., 12, 713 (2010)
- D’Alessandro M, Smit B, Long JR, Angew. Chem.-Int. Edit., 49, 6058 (2010)
- Jones W, Maginn EJ, ChemSusChem., 3, 863 (2010)
- Takeda Y, Okumura S, Sasaki I, Minakata S, Org Lett., 14, 4874 (2012)
- Kim ST, Kang JW, Lee J, Min BM, Korean J. Chem. Eng., 28(12), 2275 (2011)
- Lepaumier H, Picq D, Carrette PL, Ind. Eng. Chem. Res., 48(20), 9061 (2009)
- Goff GS, Rochelle GT, Ind. Eng. Chem. Res., 45(8), 2513 (2006)
- Gouedard C, Picq D, Launay F, Carrette PL, Int. J. Greenh. Gas Con., 10, 244 (2012)
- Karl M, Wright RF, Berglen TF, Denby B, Int. J. Greenh. Gas Con., 5, 439 (2011)
- Mani F, Peruzzini M, Stoppioni P, Green Chem., 8, 995 (2006)
- Veltman K, Sing B, Hertwich EG, Environ. Sci. Technol., 44, 1496 (2010)
- Zheng C, Tan J, Wang YJ, Luo GS, Ind. Eng. Chem. Res., 51(34), 11236 (2012)
- Jessop PG, Heldebrant DJ, Li X, Eckert CA, Liotta CL, Nature, 436, 1102 (2005)
- Su X, Cunningham MF, Jessop PG, Chem. Commun., 49, 2655 (2013)
- Su X, Robert T, Mercer SM, Humphries C, Cunningham MF, Jessop PG, Chem.-Eur. J., 19, 5595 (2013)
- Jessop PG, Phan L, Carrier A, Robinson S, Durr CJ, Harjani JR, Green Chem., 12, 809 (2010)
- Liu Y, Jessop PG, Cunningham MF, Eckert CA, Liotta CL, Science, 313, 958 (2006)
- Kim M, Park J, Chem. Commun., 46, 2507 (2010)
- Klimaszewski K, Borun A, Bald A, Sengwa RJ, J. Chem. Eng. Data, 57(11), 3164 (2012)
- Li CP, Zhang JB, Zhang T, Wei XH, Zhang EQ, Yang N, Zhao NN, Su M, Zhou H, J. Chem. Eng. Data, 55(9), 4104 (2010)
- Maheswari U, Palanivelu K, J. CO2 Utilization, 6, 45 (2014)
- Li J, You CJ, Chen LF, Ye YM, Qi ZW, Sundmacher K, Ind. Eng. Chem. Res., 51(37), 12081 (2012)
- Li J, Chen LF, Ye YM, Qi ZW, J. Chem. Eng. Data, 59(6), 1781 (2014)
- Shang JP, Liu SM, Ma XY, Lu LJ, Deng YQ, Green Chem., 14, 2899 (2012)
- Wang HB, Jessop PG, Liu GJ, ACS Macro Lett., 1, 944 (2012)
- Srikanth CS, Chuang SSC, J. Phys. Chem. C, 117, 9196 (2013)
- Blasucci V, Dilek C, Huttenhower H, John E, Llopis-Mestre V, Pollet P, Eckert CA, Liotta CL, Chem. Commun., 116 (2009)
- Danon A, Stair PC, Weitz E, J. Phys. Chem. C, 115, 11540 (2011)
- Dibenedetto A, Aresta M, Fragale C, Narracci M, Green Chem., 4, 439 (2002)
- Phan L, Andreatta JR, Horvey LK, Edie CF, Luco AL, Mirchandani A, Darensbourg DJ, Jessop PG, J. Org. Chem., 73, 127 (2008)
- Heldebrant DJ, Jessop PG, Thomas CA, Eckert CA, Liotta CL, J. Org. Chem., 70, 5335 (2005)
- Scott LM, Robert T, Harjani JR, Jessop PG, RSC Adv., 2, 4925 (2012)
- Peeters ANM, Faaij APC, Turkenburg WC, Int. J. Greenh. Gas Con., 1, 396 (2007)
- Barzagli F, Mani F, Peruzzini M, Energy Environ. Sci., 2, 322 (2009)
- Enrico A, Eoghan PD, Laurie C, Lawrence BA, Andrew RB, Sci. Rep., 4, 7304 (2014)
- Heldebrant DJ, Yonker CR, Jessop PG, Phan L, Energy Environ. Sci., 1, 487 (2008)
- Packer M, Energy Policy, 37(9), 3428 (2009)