The new method for producing hydrogen-enriched syngas (HRG) by steam gasification of coal using molten blast furnace slag (BFS) as heat carrier was established. In order to achieve the HRG production, a gasification system using this method was proposed and constructed. The carbon gasification efficiency (CE), hydrogen yield (YH2) and cold gasification efficiency (CGE) in the molten slag reactor were measured, and the effects of temperature, S/C (steam to coal) ratio and coal type on the reaction performance were accessed. The results indicated that the preferred temperature was 1350 degrees C, which ensured the miscibility of coal-steam-slag, the diffusion of reactant in molten BFS as well as recovering waste heat. The optimal S/C ratio was 1.5-2.0 for producing HRG. Under these conditions, the hydrogen fraction was higher than 63% and the gas yield reached to 1.89 Nm(3)/kg. The CE and CGE were higher than 96% and 102%, respectively. The YH2 also reached to 1.20 Nm(3)/kg. Meanwhile, different types of coal were successfully gasified in molten BFS reactor for producing HRG. The proposed method enhanced the gasification efficiency of different types of coal, recovered the BFS waste heat effectively, and had important guidance for industrial manufacture. (C) 2016 Elsevier Ltd. All rights reserved.