화학공학소재연구정보센터
Journal of Chemical Thermodynamics, Vol.99, 1-10, 2016
The effect of the alkyl chain length on physicochemical features of (ionic liquids plus gamma-butyrolactone) binary mixtures
Densities and viscosities were determined and analysed for gamma-butyrolactone (GBL) binary mixtures with 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide ionic liquids (where alkyl = ethyl, hexyl, octyl) as a function of temperature at atmospheric pressure (p = 0.1 MPa) and over the whole composition range. Excess molar volumes have been calculated from the experimental densities and were fitted using Redlich-Kister's polynomial equation. Other volumetric parameters have been also calculated in order to obtain information about interactions between GBL and imidazolium based ionic liquids with different alkyl chain length. From the viscosity measurements, the Angell strength parameter was calculated for pure ionic liquids indicating that all investigated electrolytes are "fragile" liquids. (C) 2016 Elsevier Ltd. All rights reserved.