La2Zr2O7 microspheres were directly prepared by cathode plasma electrolysis (CPE) in the electrolyte of Zr(NO3)(4)center dot 5H(2)O and La(NO3)(3)center dot 6H(2)O. Compared with high temperature sintering methods, the energy of plasma was completely used by CPE and made it possible to prepare the microspheres without calcining. The diameters of microspheres were mostly in the range of 0.5-5 mu m and the microspheres consisted of fluorite and pyrochlore structures of La2Zr2O7. Moreover, the microspheres possessed potential photocatalytic activity and fluorescence property, owing to the high crystallinity and large surface area of the microspheres. (C) 2016 Elsevier Inc. All rights reserved.