NaA zeolite membranes were synthesized on top of both disk and tubular porous stainless steel substrates by the secondary growth method. The support seed stage was optimized, considering the seed synthesis conditions and the deposition method. The formation of the NaA zeolite on both the membrane and the residual powder collected at the bottom of the vessel after synthesis was corroborated by X-ray diffraction (XRD). Scanning electron microscopy (SEM) revealed the formation of a film with well-defined crystals with a cubic morphology characteristic of the NaA zeolite. The support modification with 3-aminopropyltriethoxysilane improved the morphology and stability of the NaA zeolite membranes synthesized on top of porous stainless steel substrates. When vacuum was applied only in the last hydrothermal synthesis stage, a smooth zeolite layer was obtained on top of porous stainless steel supports. The single gas (H-2, N-2, CO2 and CH4) and mixture (H-2/N-2 and H-2/CH4) perm-selective properties of the tubular membranes were evaluated as a function of temperature and pressure. Separation factors higher than the Knudsen coefficient were obtained in all membranes. The single gas H-2 and CO2 permeation flux of the membranes increased with temperature indicating a preponderance of the activated diffusion over the Knudsen diffusion. The higher H-2/CO2 ideal separation factors were 7.6 and 5.6 for the more selective tubular membranes, at 453 K and 100 kPa. (C) 2016 Elsevier B.V. All rights reserved.