화학공학소재연구정보센터
Journal of Molecular Catalysis A-Chemical, Vol.417, 122-125, 2016
Micelle-based nanoreactors containing Ru-porphyrin for the epoxidation of terminal olefins in water
This contribution introduces a strategy to use Ru(II)-porphyrin complexes as catalysts for the epoxidation of alkenes in water. The design is based on shell cross-linked micelle-based nanoreactors with hydrophobic cores and hydrophilic shells as supports for the Ru(II) porphyrin complexes. The supported complexes are efficient catalysts for oxidation reactions, specifically the selectively oxidation of alkenes to epoxides. The presented strategy is the first system that allows for running Ru-catalyzed epoxidation reactions in water. (C) 2016 Elsevier B.V. All rights reserved.