화학공학소재연구정보센터
Materials Research Bulletin, Vol.79, 69-72, 2016
Synthesis and photoluminescent properties of Sr(1-x)Si2O2N2: xEu(2+) phosphor prepared by polymer metal complex method for WLEDs applications
Green emitting Sr(1-x)Si2O2N2: xEu(2+) (x=0, 0.02, 0.04, 0.06, 0.08 and 0.1) phosphors were synthesized by polymer metal complex or pechini method. The XRD results confirm the formation of a pure phase at 1400 degrees C for 3 h. The SEM and particles size results indicate that the prepared phosphor consists of a polyhedral crystalline shape with well dispersed and the average particle size around 6.5 mu m. The maximum PL intensity was found at 0.04% Eu2+ with a wide emission band between 460 and 640 nm and a green emission peak at 531.4 nm. The external quantum efficiency of 0.04% Eu2+ sample was 43.13%. The results indicate that pechini method is an alternative way and close in efficiency to the solid state method to prepare SrSi2O2N2 phosphor with higher homogeneity and more uniform size distribution for near UV and blue region applications for white light emitting diodes WLEDs. (C) 2016 Published by Elsevier Ltd.