화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.39, 162-175, July, 2016
DOI10.1016/j.jiec.2016.05.024  Export Citation
Ultrasonic modified corn pith for the sequestration of dye from aqueous solution
R. Jothirani†, P. Senthil Kumar1, †, A. Saravanan1, †, Abishek S. Narayan1, †, and Abhishek Dutta1, †
  • Department of Chemistry, Adhiparasakthi Engineering College, Melmaruvathur 603 319, India
  • 1Department of Chemical Engineering, SSN College of Engineering, Chennai 603 110, India
E-mail:, , , ,
In this research, the ultrasonic waves were used to prepare the novel material from corn pith for the removal of malachite green (MG) dye from aqueous solution. The prepared material was characterized by BET, FTIR, SEM, TGA and XRD analyses. Adsorption system followed Freundlich and pseudo-first order kinetic models. Langmuir monolayer capacity of the adsorbent was calculated as 488.3 mg g-1 which was higher as compared with other local materials. Adsorption thermodynamics was found to be exothermic and spontaneous. The adsorber was designed using Freundlich model. The novel material showed good adsorption capacity for sequestration of MG dye from wastewater.
Keywords:Design;Isotherms;Malachite green dye;Ultrasonics;Separation
  1. Kumari K, Abraham TE, Bioresour. Technol., 98(9), 1704 (2007)
  2. Ghaedi M, Ghaedi AM, Abdi F, Roosta M, Vafaei A, Asghari A, Ecotox. Environ. Safe., 96, 110 (2013)
  3. Ghaedi M, Ghobadzadeh P, Kokhdan SN, Soylak M, Arab. J. Sci. Eng., 38, 1691 (2013)
  4. Mittal H, Parashar V, Mishra SB, Mishra AK, Chem. Eng. J., 255, 471 (2014)
  5. Roosta M, Ghaedi M, Shokri N, Daneshfar A, Sahraei R, Asghari A, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 118, 55 (2014)
  6. Roosta M, Ghaedi M, Daneshfar A, Sahraei R, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 122, 223 (2014)
  7. Zheng Y, Zhu YF, Wang AQ, Chem. Eng. J., 257, 66 (2014)
  8. Ghaedi M, Ghaedi AM, Hossainpour M, Ansari A, Habibi MH, Asghari AR, J. Ind. Eng. Chem., 20(4), 1641 (2014)
  9. Ghaedi M, Ghaedi AM, Negintaji E, Ansari A, Mohammadi F, J. Ind. Eng. Chem., 20(6), 4332 (2014)
  10. Sarkar AK, Pal A, Ghorai S, Mandre NR, Pal S, Carbohydr. Polym., 111, 108 (2014)
  11. Wang D, Liu L, Jiang X, Yu J, Chen X, Colloids Surf. A: Physicochem. Eng. Asp., 466, 166 (2015)
  12. Malik R, Ramteke DS, Wate SR, Waste Manage., 27, 1129 (2007)
  13. Gupta VK, Sharma G, Pathania D, Kothiyal NC, J. Ind. Eng. Chem., 21, 957 (2015)
  14. Zhou Y, Min Y, Qiao H, Huang Q, Wang E, Ma T, Int. J. Biol. Macromol., 74, 271 (2015)
  15. Khan AA, Ahmad R, Khan A, Mondal PK, Arab. J. Chem., 6, 361 (2013)
  16. Shirmardi M, Mahvi AH, Hashemzadeh B, Naeimabadi A, Hassani G, Niri MV, Korean J. Chem. Eng., 30(8), 1603 (2013)
  17. Zhang XM, Yu HW, Yang HJ, Wan YC, Hu H, Zhai Z, Qin JM, J. Colloid Interface Sci., 437, 277 (2015)
  18. Stammati A, Nebbia C, Angelis ID, Albo AG, Carletti M, Rebecchi C, Zampaglioni F, Dacasto M, In Vitro, 19, 853 (2005)
  19. Anbia M, Ghaffari A, J. Iran. Chem. Soc., 8, 67 (2011)
  20. Rong X, Qiu F, Qin J, Yan J, Zhao H, Yang D, J. Ind. Eng. Chem., 20(5), 3808 (2014)
  21. Saygi KO, Tuzen M, Soylak M, Elci L, J. Hazard. Mater., 153(3), 1009 (2008)
  22. Serencam H, Gundogdu A, Uygur Y, Kemer B, Bulut VN, Duran C, Soylak M, Tufekci M, Bioresour. Technol., 99(6), 1992 (2008)
  23. Zhang H, Tang Y, Liu XA, Ke ZG, Su X, Cai DQ, Wang XQ, Liu YD, Huang Q, Yu ZL, Desalination, 274(1-3), 97 (2011)
  24. Tang H, Zhou W, Zhang L, J. Hazard. Mater., 209-210, 218 (2012)
  25. Yagub MT, Sen TK, Afroze S, Ang HM, Adv. Colloid Interface Sci., 209, 172 (2014)
  26. Sharma YC, J. Chem. Eng. Data, 56(3), 478 (2011)
  27. Kuhar F, Papinutti L, J. Environ. Manage., 124, 1 (2013)
  28. Daneshvar N, Ayazloo M, Khataee AR, Pourhassan M, Bioresour. Technol., 98(6), 1176 (2007)
  29. Bekci Z, Seki Y, Cavas L, J. Hazard. Mater., 161(2-3), 1454 (2009)
  30. Chowdhury S, Mishra R, Saha P, Kushwaha P, Desalination, 265(1-3), 159 (2011)
  31. Jalil AA, Triwahyono S, Yaakob MR, Azmi ZZA, Sapawe N, Kamarudin NHN, Setiabudi HD, Jaafar NF, Sidik SM, Adam SH, Hameed BH, Bioresour. Technol., 120, 218 (2012)
  32. Rios JB, Malvar RA, Jung HJG, Santiago R, Phytochemistry, 72, 365 (2011)
  33. Asfaram A, Ghaedi M, Goudarzi A, Soylak M, RSC Adv., 5, 39084 (2015)
  34. Unsal YE, Soylak M, Tuzen M, Environ. Monit. Assess., http://dx.doi.org/10.1007/s10661-015-4427-4, 187 (2015)
  35. Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
  36. Freundlich HMF, J. Phys. Chem., 57, 385 (1906)
  37. Yang RT, Doong SJ, Am. Inst. Chem. Eng., 31, 1829 (1985)
  38. Lagergren S, Kungliga. Svenska. Vetensk. Handl., 24, 1 (1898)
  39. Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
  40. Low MJD, Chem. Rev., 60, 267 (1960)
  41. Weber WJ, Morris JC, J. Sanit. Eng. Div. Am. Soc. Civ. Eng., 89, 31 (1963)
  42. Akar E, Altinisik A, Seki Y, Ecol. Eng., 52, 19 (2012)
  43. Zhang G, Yi L, Deng H, Sun P, J. Environ. Sci., 26, 1203 (2014)
  44. Gusmao KAG, Gurgel LVA, Melo TMS, Gil LF, Dyes Pigment., 92, 967 (2012)
  45. Ahmad MA, Alrozi R, Chem. Eng. J., 171(2), 510 (2011)
  46. Li XL, Li YF, Zhang SD, Ye ZF, Chem. Eng. J., 183, 88 (2012)
  47. Ghaedi M, Ansari A, Habibi MH, Habibi AR, J. Ind. Eng. Chem., 20(1), 17 (2014)
  48. Gong RM, Jin YB, Chen FY, Chen J, Liu ZL, J. Hazard. Mater., 137(2), 865 (2006)
  49. Bradder P, Ling SK, Wang SB, Liu SM, J. Chem. Eng. Data, 56(1), 138 (2011)
  50. Hameed BH, El-Khaiary MI, J. Hazard. Mater., 159(2-3), 574 (2008)
  51. Mohammadi A, Lakouraj MM, Barikani M, React. Funct. Polym., 83, 14 (2014)
  52. Baek MH, Ijagbemi CO, Se-Jin O, Kim DS, J. Hazard. Mater., 176(1-3), 820 (2010)
  53. Arellano-Cardenas S, Lopez-Cortez S, Cornejo-Mazon M, Mares-Gutierrez JC, Appl. Surf. Sci., 280, 74 (2013)
  54. Hajati S, Ghaedi M, Yaghoubi S, J. Ind. Eng. Chem., 21, 760 (2015)