In case of blending between chitosan and melamine, compatibility was very well when they were dissolved with solution of acetic acid. Novel polymer membranes were synthesized by using formaldehyde reagent. Preparations of characteristic membranes were studied in composition rate of chitosan versus melamine at room temperature. Electric properties as membrane electric potential, ion transport, permeability coefficient, diffusion coefficient were studied using prepared chitosan composite membranes. The results were that transports of anions were higher then that of cations and membrane response were good in low concentrated solutions then high its.