Chemical Engineering Journal, Vol.300, 384-393, 2016
Performance evaluation of solid oxide carbon fuel cells operating on steam gasified carbon fuels
We investigated the operating characteristics of solid oxide carbon fuel cells (SO-CFCs) integrated with a steam gasifier that used carbonaceous fuels, including activated carbon and biomass driven charcoal. Steam gasification was carried out in a specially designed gasifier, which was directly integrated with a solid-oxide based carbon fuel cell. We studied the effects of gasification temperature, steam flow rate and catalyst addition on the electrochemical performance of SO-CFC, and the results showed that among the three tested fuels, activated carbon with a K2CO3 catalyst performed the best. At 850 degrees C, maximum power density values of 108 mW/cm(2), 161 mW/cm(2) and 181 mW/cm(2) were achieved when the SO-CFC was operated using activated carbon, biomass driven charcoal and activated carbon with a K2CO3 catalyst, respectively. The SO-CFC operated continuously for 100 h and it showed relatively stable performance. This study suggests that by using a catalytic steam gasifier integrated with the SO-CFC, solid carbon fuel resources can be used for power generation with higher efficiency and minimal carbon footprint. (C) 2016 Elsevier B.V. All rights reserved.
Keywords:Solid oxide carbon fuel cell;Steam gasification;Activated carbon;Biomass charcoal;Electrochemical performance