화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.41, No.19, 8176-8183, 2016
Development of a stand-alone steam methane reformer for on-site hydrogen production
A small, stationary reformer designed as a stand-alone and self-sustaining type was developed for on-site hydrogen (H-2) production. We created a compact reformer to produce H-2 at a rate of 1 Nm(3)/h using the previously reported reaction kinetics of steam methane reforming (SMR). Both catalysts for the compact reformer - i.e., 15 wt% and 20 wt% Ni/gamma-Al2O3 - showed good activity, with CH4 conversion exceeding 90% at 655 degrees C and a contact time of 3.0 gcath/mol, which were considered critical thresholds in the development of a small, compact stationary reformer. At an H-2 production rate of 1 Nm(3)/h, the catalyst amount was calculated to be 167.8 g and the reformer length required to charge the catalyst was 613 mm, with a diameter of 1 inch. The CH4 conversion and H-2 production rates achieved with the compact reformer using the 20 wt% Ni/gamma-Al2O3 catalyst at 738 degrees C were 97.9% and 1.22 Nm(3)/h, respectively. Furthermore, a heat -exchanger type reformer was developed to efficiently carry out the highly endothermic SMR reaction for on-site H-2 production. This reformer comprised a tube side (in which the catalysts were charged and the SMR reaction took place by feeding the reactants) and a shell side (in which the heat for the endothermic reaction was supplied by CH4 combustion). Reforming activities were evaluated using the active 20 wt% Ni//gamma-Al2O3 catalyst, depending on the reactants' gas hourly space velocity (GHSV). The H-2 production rate increased as the GHSV increased. Finally, the reformer produced a CH4 conversion of 98.0% and an H-2 production rate of 1.97 Nm(3)/h at 745 degrees C, as well as a high reactants' GHSV of 10,000 Therefore, the heat exchanger type reformer proved to be an effective system for conducting the highly endothermic SMR reaction with a high reactants' GHSV to yield a high rate of H-2 production. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.