Dye-sensitized photoelectrochemical (DSPEC) device for solar hydrogen generation is gaining significant attention. However, there are some fundamental challenges such as dye desorption, aggregation and photo-stability impediment its long term performance. To circumvent the subset of these challenges herein, we demonstrate click chemistry based fabrication methodology to develop optically complemented multiple dyes anchored P25-TiO2 scaffold over ITO plate. A photocurrent density of similar to 2.1 mA/cm(2) and ABPE of similar to 1.0% have been obtained with optically complemented multiple dyes (N719 and FITC) clicked P25-TiO2@ITO photoanode compared to single N719 (ABPE similar to 0.72%), N749 (ABPE similar to 0.60%), and N3 (ABPE similar to 0.51%) at 0.7 V applied bias. We trust that proposed approach can pave a pathway to anchor combination of different optically complemented dyes over number of semiconductor photocatalyst. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.