Transfer hydrogenation of acetophenone and methyl benzoylformate with 2-propanol has been studied on rhodium nanoparticles obtained by the reduction of rhodium(I) complexes in the presence of optically active compounds, including chiral diamine S,S-DIODMA, (4S,5S)-N-4,N-4,N-5,N-5,2,2-hexamethyl-4,5-bis-(aminomethylene)-1,3-dioxolane, quaternary diammonium salt (4S,5S)-(-)-N-1,N-4-dibenzyl-2,3-dihydroxy-N-1,N-1,N-4,N-4-tetramethylbutane-1,4-diammonium dichloride, and (8S,9R)-(-)-cinchonidine. Increasing the modifier to Rh ratio leads to an increase in the enantiomeric excess (ee) of the reaction products. The greatest ee values (43.8% for (R)-1-phenylethanol and 58.2% for the methyl ester of (R)-mandelic acid) were achieved at (8S,9R)-(-)-cinchonidine/Rh ratios of 9:1 and 3:1, respectively. (C) 2016 Elsevier B.V. All rights reserved.