It's important to reduce recombination of electrons and holes and enhance charge transfer through fine controlled interfacial structure. In this work, novel graphitic-C3N4 (g-C3N4)/Ag2WO4/Ag ternary photo catalyst has been synthesized by deposition of Ag2WO4 onto g-C3N4 template and followed by sun light reduction of Ag2WO4 into Ag2WO4/Ag. As-prepared g-C3N4/Ag2WO4/Ag presented significantly enhanced photocatalytic performance in degrading methylene blue (MB) under 410 nm LED light irradiation. Metallic Ag-o is used as plasmonic hot spots to generate high energy charge carriers. Optimal g-C3N4 content has been confirmed to be 40 wt%, corresponding to apparent pseudo-first-order rate constant kapp of 0.0298 min(-1), which is 3.3 times and 37.3 times more than that of pure g-C3N4 and Ag2WO4, respectively. This novel ternary g-C3N4/Ag2WO4/Ag structure material is an ideal candidate in environmental treatment and purifying applications. (C) 2016 Elsevier B.V. All rights reserved.