Cyclic voltammetry and electrochemical impedance spectroscopy were used to investigate the deposition of antimony telluride or copper telluride from ionic liquid consisting in mixture of choline chloride with oxalic acid. In addition, the cathodic process during copper telluride formation was studied in the mixture of choline chloride with ethylene glycol. The results indicate that the Pt electrode is first covered with a Te layer, and then the more negative polarisation leads to the deposition of SbxTey or CuxTey semiconductor compounds. Thin films were deposited on copper and carbon steel at 60-70 degrees C and were characterised by scanning electron microscopy, energy X-ray dispersive spectroscopy (EDS), and X-ray diffraction (XRD). Their stoichiometry depends on the bath composition and applied potential. EDS and XRD patterns indicate the possible synthesis of stoichiometric Sb2Te3 phase and Cu2Te, Cu5Te3, and Cu2.8Te2 phases, respectively, by controlling the ratio of ion concentrations in ionic liquid electrolytes and deposition potential. (C) 2016 Elsevier B.V. All rights reserved.