화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.41, 10-22, September, 2016
DOI10.1016/j.jiec.2016.07.005  Export Citation
Synthesis and characterization of some nonionic surfactants as corrosion inhibitors for steel in 1.0 M HCl (Experimental and computational study)
M.A. Bedair†, S.A. Soliman, and M.S. Metwally
  • Department of Chemistry, Faculty of Science (Men’s Campus), Al-Azhar University, Nasr City 11884, Cairo, Egypt
E-mail:
Synthesis, adsorption and corrosion inhibiting effect of three surfactants consist of Schiff bases as hydrophobic part and poly ethylene glylcol (poly ethylene oxide) as hydrophilic part on steel in 1.0 M HCl was investigated using weight loss, Electrochemical Impedance, potentiodynamic polarization techniques and computational methods. The experimental findings revealed that these compounds inhibited the corrosion reaction in 1.0 M HCl environment. Polarization curves revealed that the used inhibitors represent mixed-type inhibitors. There was a good correlation between the experimental results and quantum chemical parameters of the surfactants. Molecular dynamic simulation indicated that these surfactants were adsorbed on the metal surface.
Keywords:Weight loss;Polarization;Electrochemical impedance spectroscopy;Density function theory;Molecular dynamics
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