화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.41, 50-61, September, 2016
DOI10.1016/j.jiec.2016.07.002  Export Citation
Dual-end-functionalized tin (Sn)-phyllosilicates for the esterification of oleic acid
Bora Nam, Hyun Uk Lee1, So Young Park1, Byung-Chul Son2, Go-Woon Lee3, Ji-Yeon Park†, and Young-Chul Lee4, †
  • Biomass and Waste Energy Laboratory, Korea Institute of Energy Research (KIER), 152 Gajeong-ro, Yuseong-gu, Daejeon 305-343, Republic of Korea
  • 1Advanced Nano-Surface Research Group, Korea Basic Science Institute (KBSI), Daejeon 34133, Republic of Korea
  • 2Research Analysis Center, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Republic of Korea
  • 3Quality Management Team, Korea Institute of Energy Research (KIER), 152 Gajeongro, Yuseong-gu, Daejeon 305-343, Republic of Korea
  • 4Department of BioNano Technology, Gachon University, 1342 Seongnamdaero, Sujeong-gu, Seongnam-si, Gyeonggi-do 13120, Republic of Korea
E-mail:,
We designed dual-end-functionalized tin (Sn)-phyllosilicate, where the -SH functional groups were subsequently oxidized for .SO3H/SO4H functionalities in a Brønsted acid with/without NH2 functional groups in a Bronsted base. Dual-end-functionalized tin (Sn)-phyllosilicates [MTES:APTS = 1.0:0.11, MTES:TEOS = 1.0:0.11 and 1.0:0.43, v/v] were fabricated where the inorganic framework of Sn species can function as a Lewis acid. The Sn-phyllosilicates with dual acids were applied to esterify oleic acid and produce oleic acid-methyl-ester to test their feasibility as fatty-acid-conversion solid catalysts. In the absence of amine groups, the increase in ratio of tetraethyl orthosilicate (TEOS) to (3-mercaptopropyl)-trimethoxysilane (MTES) for the synthesis of Sn-phyllosilicates (MTES:TEOS = 1.0:0.11 and 1.0:0.43, v/v) increased the recovery of Sn-phyllosilicate in the solvent media and gradually decreased the oleic acidmethyl-ester production efficiency (%) of the oleic acid conversion. At the fixed 2.0 wt% Sn-phyllosilicate (MTES:APTS = 1.0:0.11, v/v) loading and oleic acid:MeOH weight ratio = 1:1, an 80 ℃ reaction temperature and 4 h reaction time were determined to be the optimal conditions for the oleic acidmethyl-ester production, which had ~90% oleic acid conversion efficiency. When the Sn-phyllosilicate (MTES:APTS = 1.0:0.11, v/v) loading was increased from 0.1 to 5.0 wt% at 80 ℃ and 4 h, the fatty-acid conversion efficiency (%) of oleic acid gradually increased from 39.16 to 92.23%. In contrast, Snphyllosilicate (MTES:TEOS = 1.0:0.43) had the lowest oleic acid conversion efficiency (%) but the highest catalyst recovery. In summary, this study presents a facile method to produce oleic acid conversion catalysts on an industrial scale.
Keywords:Tin (Sn)-phyllosilicate;Dual-end functionalization;Bronsted acid/base;Lewis acid;Esterification
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