Journal of Industrial and Engineering Chemistry, Vol.41, 130-140, September, 2016
Construction of TiO2 hollow nanosphere/g-C3N4 composites with superior visible-light photocatalytic activity and mechanism insight
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An interlayer structure hybrid photocatalyst of TiO2 hollow sphere/g-C3N4 (TOCN) has been successfully constructed via a facile impregnation process. The photocatalytic activity was evaluated by degrading Rhodamine B under visible irradiation. TOCN-2 with 33 wt.% g-C3N4 had much higher photocatalytic efficiency (98.09%) than pure g-C3N4 (18.62%) and TiO2 hollow sphere (16.37%). Significantly, TOCN-2 showed much superior photocatalytic performance than TiO2 nanoparticle/g-C3N4 composite (53.16%), indicating the hollow morphology of TiO2 also played a crucial role for RhB degradation. In TOCN system, both the morphology effect of TiO2 and the synergistic effects between TiO2 and g-C3N4 resulted in significantly enhancing photocatalytic performance.
Keywords:TiO2 hollow spheres;g-C3N4;Visible-light photocatalytic activity;Interlayer structure;Synergistic effects
- Guo H, Zheng Z, Chen J, Weng W, Huang M, J. Ind. Eng. Chem., 36, 306 (2016)
- Pawar RC, Lee CS, Appl. Catal. B: Environ., 144, 57 (2014)
- Di J, Xia JX, Ge YP, Li HP, Ji HY, Xu H, Zhang Q, Li HM, Li MN, Appl. Catal. B: Environ., 168-169, 51 (2015)
- Ahn CI, Koo HM, Jo JM, Roh HS, Lee JB, Lee YJ, Jang EJ, Bae JW, Appl. Catal. B: Environ., 180, 139 (2016)
- Kim JR, Kan E, J. Ind. Eng. Chem., 21, 644 (2015)
- Huo P, Tang Y, Zhou M, Li J, Ye Z, Ma C, Yu L, Yan Y, J. Ind. Eng. Chem., 37, 340 (2016)
- Maruthamani D, Divakar D, Kumaravel M, J. Ind. Eng. Chem., 30, 33 (2015)
- Appavu B, Kannan K, Thiripuranthagan S, J. Ind. Eng. Chem., 36, 184 (2016)
- Touati A, Hammedi T, Najjar W, Ksibi Z, Sayadi S, J. Ind. Eng. Chem., 35, 36 (2016)
- Yao BH, Peng C, Zhang W, Zhang QK, Niu JF, Zhao J, Appl. Catal. B: Environ., 174-175, 77 (2015)
- Touati A, Hammedi T, Najjar W, Ksibi Z, Sayadi S, J. Ind. Eng. Chem., 35, 36 (2016)
- Jabbari V, Hamadanian M, Karimzadeh S, Villagran D, J. Ind. Eng. Chem., 35, 132 (2016)
- Zhang J, Zhang L, Zhou S, Chen H, Zhong H, Zhao Y, Wang X, J. Ind. Eng. Chem., 20(5), 3884 (2014)
- Ullah K, Meng ZD, Ye S, Zhu L, Oh WC, J. Ind. Eng. Chem., 20(3), 1035 (2014)
- Lu DZ, Fang PF, Liu XZ, Zhai SB, Li CH, Zhao XN, Ding JQ, Xiong RY, Appl. Catal. B: Environ., 179, 558 (2015)
- Nguyen-Phan T, Luo S, Vovchok D, Llorca J, ACS Catal., 6, 407 (2016)
- Yuan YJ, Ye ZJ, Lu HW, Hu B, ACS Catal., 6, 532 (2016)
- Chen YF, Huang WX, He DL, Situ Y, Huang H, ACS Appl. Mater. Interface, 6, 14405 (2014)
- Ma K, Yehezkeli O, Domaille DW, Funke HH, Cha JN, Angew. Chem.-Int. Edit., 54, 11490 (2015)
- Pawar RC, Kang S, Ahn SH, Lee CS, RSC Adv., 5, 24281 (2015)
- Pawar RC, Khare V, Lee CS, J. Chem. Soc.-Dalton Trans., 43, 12514 (2014)
- Jiang DL, Chen LL, Xie JM, Chen M, J. Chem. Soc.-Dalton Trans., 43, 4878 (2014)
- She XJ, Liu L, Ji HY, Mo Z, Li YP, Huang LY, Du DL, Xu H, Li HM, Appl. Catal. B: Environ., 187, 144 (2016)
- Hong YZ, Li CS, Zhang GY, Meng YD, Yin BX, Zhao Y, Shi WD, Chem. Eng. J., 299, 74 (2016)
- Zhang JF, Hu YF, Jiang XL, Chen SF, Meng SG, Fu XL, J. Hazard. Mater., 280, 713 (2014)
- Li ZS, Yang SY, Zhou JM, Li DH, Zhou XF, Ge CY, Fang YP, Chem. Eng. J., 241, 344 (2014)
- Huang LY, Xu H, Li YP, Li HM, Cheng XN, Xia JX, Xu YG, Cai GE, J. Chem. Soc.-Dalton Trans., 42, 8606 (2013)
- Shao LQ, Jiang DL, Xiao P, Zhu LM, Meng SC, Chen M, Appl. Catal. B: Environ., 198, 200 (2016)
- Chang F, Zhang J, Xie YC, Chen J, Li CL, Wang J, Luo JR, Deng BQ, Hu XF, Appl. Surf. Sci., 311, 574 (2014)
- Tong ZW, Yang D, Xiao TX, Tian Y, Jiang ZY, Chem. Eng. J., 260, 117 (2015)
- Gu LA, Wang JY, Zou ZJ, Han XJ, J. Hazard. Mater., 268, 216 (2014)
- Huang ZA, Sun Q, Lv KL, Zhang ZH, Li M, Li B, Appl. Catal. B: Environ., 164, 420 (2015)
- Li K, Gao SM, Wang QY, Xu H, ACS Appl. Mater. Interface, 7, 9023 (2015)
- Li GY, Nie X, Chen JY, Jiang Q, Water Res., 86, 17 (2015)
- Hu J, Wang XG, Liu LQ, Wu LM, J. Mater. Chem. A, 2, 19771 (2014)
- Hu J, Chen M, Fang XS, Wu LM, Chem. Soc. Rev., 40, 5472 (2011)
- Jia CC, Yang P, Chen HS, Wang JP, CrystEngComm, 17, 2940 (2015)
- Lei BX, Zeng LL, Zhang P, Zheng XF, Wu YS, Fu J, Sun ZF, RSC Adv., 4, 29099 (2014)
- Wang Z, Hou JG, Yang C, Jiao SQ, Huang K, Zhu HM, Energy Environ. Sci., 6, 2134 (2013)
- Zhu Z, Lu ZY, Wang DD, Tang X, Yan YS, Shi WD, Wang YS, Gao NL, Yao X, Dong HJ, Appl. Catal. B: Environ., 182, 115 (2016)
- Ding J, Liu QQ, Zhang ZY, Liu X, Zhao JQ, Cheng SB, Zong BN, Dai WL, Appl. Catal. B: Environ., 165, 511 (2015)
- Zhang ZY, Jiang DL, Li D, He MQ, Chen M, Appl. Catal. B: Environ., 183, 113 (2016)
- Li YS, Shi JL, Adv. Mater., 10, 1002 (2014)
- Wang YJ, Shi R, Lin J, Zhu YF, Energy Environ. Sci., 4, 2922 (2011)
- Shao Y, Cao CS, Chen SL, He M, Fang JL, Chen J, Li XF, Li DZ, Appl. Catal. B: Environ., 179, 344 (2015)
- Kang SF, Fang Y, Huang YK, Cui LF, Wang YZ, Qin HF, Zhang YM, Li X, Wang YG, Appl. Catal. B: Environ., 168, 472 (2015)
- Munoz-Batista MJ, Fernandez-Garcia M, Kubacka A, Appl. Catal. B: Environ., 164, 261 (2015)
- Xin XY, Xu T, Yin J, Wang L, Wang CY, Appl. Catal. B: Environ., 176-177, 354 (2015)
- Zhang XY, Sun YJ, Cui XL, Jiang ZY, Int. J. Hydrog. Energy, 37(2), 1356 (2012)
- Tian J, Leng YH, Cui HZ, Liu H, J. Hazard. Mater., 299, 165 (2015)
- Song X, Hu Y, Zheng MM, Wei CH, Appl. Catal. B: Environ., 182, 587 (2016)
- Leshuk T, Linley S, Baxter G, Gu F, ACS Appl. Mater. Interface, 4, 6062 (2012)
- Feng ZL, Wei WR, Wang LT, Hong RY, Appl. Surf. Sci., 357, 759 (2015)
- Li W, Wu ZX, Wang JX, Elzatahry AA, Zhao DY, Chem. Mater., 26, 287 (2014)
- Lu ML, Pei ZX, Weng X, Feng WH, Fang ZB, Zheng ZY, Huang ML, Liu P, Phys. Chem. Chem. Phys., 16, 21280 (2014)
- Li H, Sun YJ, Cai B, Gan S, Han DX, Niu L, Wu TS, Appl. Catal. B: Environ., 170-171, 206 (2015)
- Chen YB, Li DZ, Chen J, Wang JX, Meng SG, Xian JJ, Fu XZ, Shao Y, Appl. Catal. B: Environ., 129, 403 (2013)
- Tian N, Huang HW, J. Chem. Soc.-Dalton Trans., 44, 4297 (2015)