화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.41, 130-140, September, 2016
Construction of TiO2 hollow nanosphere/g-C3N4 composites with superior visible-light photocatalytic activity and mechanism insight
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An interlayer structure hybrid photocatalyst of TiO2 hollow sphere/g-C3N4 (TOCN) has been successfully constructed via a facile impregnation process. The photocatalytic activity was evaluated by degrading Rhodamine B under visible irradiation. TOCN-2 with 33 wt.% g-C3N4 had much higher photocatalytic efficiency (98.09%) than pure g-C3N4 (18.62%) and TiO2 hollow sphere (16.37%). Significantly, TOCN-2 showed much superior photocatalytic performance than TiO2 nanoparticle/g-C3N4 composite (53.16%), indicating the hollow morphology of TiO2 also played a crucial role for RhB degradation. In TOCN system, both the morphology effect of TiO2 and the synergistic effects between TiO2 and g-C3N4 resulted in significantly enhancing photocatalytic performance.
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