Production of bio-epoxide and bio-adhesive from non-edible oil

Srikanta Dinda; Nikhil Sainath Reddy Veeram; Ramesh Babu Adusumalli

Korean Journal of Chemical Engineering, Vol.33, No.10, 2915-2922, October, 2016

DOI10.1007/s11814-016-0136-0 Export Citation

Production of bio-epoxide and bio-adhesive from non-edible oil

Srikanta Dinda^†, Nikhil Sainath Reddy Veeram, and Ramesh Babu Adusumalli

Department of Chemical Engineering, BITS Pilani - Hyderabad Campus, Jawahar Nagar, Hyderabad - 500078, India

E-mail:

Epoxidation of Nahor oil was performed by H2O2 in the presence of acid catalyst at 50 ℃. It was possible to obtain around 70% epoxide yield within 8 hrs of reaction. Amberlite IR 120H showed better epoxide yield compared to H2SO4 and Dowex 50 WX8. The performance of carboxylic acids was found to be in the order of formic acid>acetic acid>propanoic acid. The curing of epoxidized nahor oil involved using ethylenediamine (EDA) and diethylenetriamine (DETA). The adhesive property of the cured resins was tested and compared with commercially available glue. The force required to detach the cardboard joint was about 36.3 N for DETA-cured resin.

Keywords:Nahor Oil;Carboxylic Acid;Acid Catalyst;Epoxy Resin;Amine Curing;Adhesive

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[1] Kim N, Li Y, Sun XS, Ind. Crop. Prod., 64, 1 (2015)

[2] Gan LH, Ooi KS, Gan LM, Goh SH, J. Am. Oil Chem. Soc., 72, 439 (1995)

[3] Borugadda VB, Goud VV, Energy Policy, 54, 75 (2014)

[4] Ewumbua MM, Darrin MH, Dennis PW, Ind. Crop. Prod., 67, 364 (2015)

[5] Padmasiri KG, Michael OB, Laleen KJ, National Sci. Found. Sri Lanka., 37, 229 (2009)

[6] Okieimen FE, Bakare OI, Okieimen CO, Ind. Crop. Prod., 15, 139 (2002)

[7] Rios LA, Weckes P, Schuster H, Hoelderich WF, J. Catal., 232(1), 19 (2005)

[8] Rangarajan B, Havey A, Grulke EA, Culnan PD, J. Am. Oil Chem. Soc., 72, 1161 (1995)

[9] Jankovic M, Fiser SS, J. Am. Oil Chem. Soc., 82, 301 (2005)

[10] Biermann U, Friedt W, Lang S, Luhs W, Machmuller G, Metzger JO, Klaas MR, Schafer HJ, Schneider MP, Angew. Chem.-Int. Edit., 39, 2206 (2000)

[11] Klaas MR, Warwel S, Ind. Crop. Prod., 9, 125 (1999)

[12] Dinda S, Goud VV, Patwardhan AV, Pradhan NC, Asia-Pac. J. Chem. Eng., 6, 870 (2011)

[13] Dinda S, Patwardhan AV, Goud VV, Pradhan NC, Bioresour. Technol., 99(9), 3737 (2008)

[14] Goud VV, Dinda S, Patwardhan AV, Pradhan NC, AsiaPac. J. Chem. Eng., 5, 346 (2010)

[15] Goud VV, Patwardhan AV, Dinda S, Pradhan NC, Chem. Eng. Sci., 62(15), 4065 (2007)

[16] Garcia FG, Leyva ME, de Queiroz AAA, Simoes AZ, Int. J. Adhes. Adhes., 31, 177 (2011)

[17] Liu Y, Yang G, Xiao HM, Feng QP, Fu ST, Int. J. Adhes. Adhes., 41, 113 (2013)

[18] Katnam KB, Comer AJ, Stanley WF, Buggy M, Young TM, Int. J. Adhes. Adhes., 37, 3 (2012)

[19] Salunkhe DK, Chavan JK, Adsule RN, Kadam SS, World Oilseeds: Chemistry, Technology and Utilization, first Ed., Van Nostrand Reinhold, New York (1992).

[20] Siggia S, Hanna JG, Quantitative Organic Analysis via Functional Groups, 4th Ed., Wiley, New York (1979).

[21] Pequot C, Standard Methods for the Analysis of Oils, Fats and Derivatives, Part-1, fifth Ed., Pergamon Press, Germany (1979).

[22] May CA, Epoxy Resins: Chemistry and Technology, Second Ed., Marcel Dekker, New York (1987).