화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.42, 23-35, October, 2016
DOI10.1016/j.jiec.2016.07.008  Export Citation
Mass transfer resistance and response surface methodology for separation of platinum (IV) across hollow fiber supported liquid membrane
Krirkratthawit Wongkaew, Thanaporn Wannachod, Vanee Mohdee, Ura Pancharoen†, Amornchai Arpornwichanop†, and Anchaleeporn W. Lothongkum1
  • Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Pathumwan, Bangkok 10330, Thailand
  • 1Department of Chemical Engineering, Faculty of Engineering, King Mongkut’s Institute of Technology Ladkrabang, Bangkok 10520, Thailand
E-mail:,
The separation of platinum (IV) from wastewater across hollow fiber supported liquid membrane was successful in reaching 96% extraction and 88% stripping using 10% (v/v) trioctylmethyl-ammonium chloride (Aliquat 336) as the extractant. The mass transfer resistances were (1/ka) 3.297 ×104 s/cm, (1/km) 0.164 ×104 s/cm, (1/ko) 3.404 ×104 s/cm and (1/K) 6.865 ×104 s/cm. The system was governed by the mass transfer resistance from the liquid-membrane. Response surface methodology was used to qualify and estimate the influence of operating conditions. Predicted model with experimental data were in good agreement at a standard deviation of 1%.
Keywords:Response surface methodology;Platinum (IV);Aliquat 336;Mass transfer;Hollow fiber supported liquid membrane
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