Synthesis and application of metal-containing ZSM-5 for the selective catalytic reduction of NOx with NH3

Enhui Yuan; Kun Zhang; Gongxuan Lu; Zunli Mo; Zhicheng Tang

Journal of Industrial and Engineering Chemistry, Vol.42, 142-148, October, 2016

DOI10.1016/j.jiec.2016.07.030 Export Citation

Synthesis and application of metal-containing ZSM-5 for the selective catalytic reduction of NOx with NH3

Enhui Yuan^{1, 2}, Kun Zhang³, Gongxuan Lu^{1, 4}, Zunli Mo⁵, and Zhicheng Tang^{1, 4, †}

¹State Key Laboratory for Oxo Synthesis and Selective Oxidation, and National Engineering Research Center for Fine Petrochemical Intermediates, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
²School of Materials Science and Engineering, Nankai University, Tianjin 300071, China
³Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China
⁴, China
⁵College of Chemistry, Northwest Normal University, Lanzhou 730070, China

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We reported a new one-pot method to synthesize Cu incorporated ZSM-5 with ethylene diamine tetraacetic acid copper disodium salt hydrate (EDTA-Cu) as copper source by a hydrothermal process. The obtained isomorphous substituted Cu-ZSM-5 exhibits more excellent reactivity for selective catalytic reduction of NOx by NH3 with long term stability than their conventional copper impregnated counterparts. The results indicate that the tetracoordinated Cu species in the ZSM-5 frameworks have superior catalytic properties than the Cu species existed outside the ZSM-5 zeolites frameworks. The novel ammonium salt complex method was used for the first time to synthesize the metal-ZSM-5 molecular sieves.

Keywords:NH3-SCR reaction;Catalytic reduction;Cu-ZSM-5;Hydrothermal stability

[References]

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Zhang YH, Drake IJ, Bell AT, Chem. Mater., 18, 2347 (2006)
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de Oliveira MLM, Silva CM, Moreno-Tost R, Farias TL, Jimenez-Lopez A, Rodriguez-Castellon E, Appl. Catal. B: Environ., 88(3-4), 420 (2009)
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[Referenced By]

[1] Abu-Zied BM, Schwieger W, Unger A, Appl. Catal. B: Environ., 84(1-2), 277 (2008)

[2] Xin HC, Koekkoek A, Yang QH, Santen RV, Li C, Hensen EJM, Chem. Commun., 48, 7590 (2009)

[3] Du X, Wang X, Chen Y, Gao X, Zhang L, J. Ind. Eng. Chem., 36, 271 (2016)

[4] Tang FS, Zhao H, Liu J, J. Mol. Catal. A-Chem., 3, 256 (2015)

[5] Shen B, Wang F, Zhao B, Li Y, Wang Y, J. Ind. Eng. Chem., 33, 262 (2016)

[6] Guo R, Zhen W, Pan W, Zhou Y, Hong J, Xu H, Jin Q, Ding C, Guo S, J. Ind. Eng. Chem., 20(4), 1577 (2014)

[7] Hammond C, Dimitratos N, Jenkins RL, Lopez-Sanchez JA, Kondrat SA, Rahim MHA, Forde MM, Thetford A, Taylor SH, Hagen H, Stangland EE, Kang JH, Moulijn JM, Willock DJ, Hutchings GJ, ACS Catal., 3, 689 (2013)

[8] Meng YT, Genuino HC, Kuo CH, Huang H, Chen SY, Zhang LC, Rossi A, Suib SL, J. Am. Chem. Soc., 135(23), 8594 (2013)

[9] Fan FT, Feng ZC, Li C, Account. Chem. Res., 43, 378 (2010)

[10] Fan WB, Duan RG, Yokoi T, Wu P, Kubota Y, Tatsumi T, J. Am. Chem. Soc., 130(31), 10150 (2008)

[11] Granger P, Parvulescu VI, Chem. Rev., 111(5), 3155 (2011)

[12] Shan WP, Liu FD, He H, Shi XY, Zhang CB, Chem. Commun., 47, 8046 (2011)

[13] Borfecchia E, Lomachenko KA, Giordanino F, Falsig H, Beato P, Soldatov AV, Boediga S, Lamberti C, Chem. Sci., 6, 548 (2015)

[14] Brandenberger S, Krocher O, Tissler A, Althoff R, Ind. Eng. Chem. Res., 50(8), 4308 (2011)

[15] Vennestrom PNR, Janssens TVW, Kustov A, Grill M, Puig-Molina A, Lundegaard LF, Tiruvalam RR, Concepcion P, Corma A, J. Catal., 309, 477 (2014)

[16] Valange S, GaBelica Z, Abdellaoui M, Clacens JM, Barrault J, Microporous Mesoporous Mater., 30, 177 (1999)

[17] Round CI, Williams CD, Latham K, Duke CVA, Chem. Mater., 13, 468 (2001)

[18] Vitale G, Molero H, Hernandez E, Aquino S, Birss V, Pereira-Almao P, Appl. Catal. A: Gen., 452, 75 (2013)

[19] Xin HC, Koekkoek A, Yang QH, van Santen R, Li C, Hensen EJM, Chem. Commun., 48, 7590 (2009)

[20] Joyner RW, Smith AD, Stockenhuber M, Berg MWEV, Phys. Chem. Chem. Phys., 6, 5435 (2004)

[21] Zhang YH, Drake IJ, Bell AT, Chem. Mater., 18, 2347 (2006)

[22] Bin F, Wei XL, Li B, Hui KS, Appl. Catal. B: Environ., 162, 282 (2015)

[23] de Oliveira MLM, Silva CM, Moreno-Tost R, Farias TL, Jimenez-Lopez A, Rodriguez-Castellon E, Appl. Catal. B: Environ., 88(3-4), 420 (2009)

[24] Zhang K, Albela B, He MY, Wang YM, Bonneviot L, Phys. Chem. Chem. Phys., 11, 2912 (2009)

[25] Zhang K, Lam KF, Albela B, Xue T, Corre T, Hou QW, Yuan EH, He MH, Bonneviot L, Chem.-Eur. J., 17, 14258 (2011)

[26] Lojacono M, Fierro G, Dragone R, Feng XB, Ditri J, Hall WK, J. Phys. Chem. B, 101(11), 1979 (1997)

[27] Giordanino F, Vennestrom PNR, Lundegaard LF, Stappen FN, Mossin S, Beato P, Bordiga S, Lamberti C, J. Chem. Soc.-Dalton Trans., 42, 12741 (2013)