Application of the Dimensional Reduction Formalism to Pb-12[Li-2(P2O7)(2)(P4O13)(2)](P4O13): a Phosphate Containing Three Types of Isolated P-O Groups

Zhang XY; Wu HP; Wang Y; Dong XY; Han SJ; Pan SL

Inorganic Chemistry, Vol.55, No.15, 7329-7331, 2016

DOI10.1021/acs.inorgchem.6b01273 Export Citation

Application of the Dimensional Reduction Formalism to Pb-12[Li-2(P2O7)(2)(P4O13)(2)](P4O13): a Phosphate Containing Three Types of Isolated P-O Groups

Zhang XY, Wu HP, Wang Y, Dong XY, Han SJ, Pan SL

A new phosphate, Pb-12[Li-2(P2O7)(2)(P4O13)(2)](P4O13), containing three types of isolated polyphosphate anionic groups [P2O7], and two types of [P4O13] has been successfully synthesized by using Li2O as dimensional reduction agent to dismantle Pb3P4O13. The isolation of [P2O7] and two types of [P4O13] with different symmetries in the title compound mainly benefits from the large number and flexible coordination of the Pb2+ cations.