Surface of n-type emitter solar cell is subjected to Oleylamine coating using standard chemical methods. The solar cell shows an increment by 16.8% in the efficiency slowly degrading in time. Investigations are carried out to isolate the passivating effect as well as degrading reactions. The degradation manifests in the form of increased reflectivity of the surface. It is expected that appropriate choice of the coatings can lead to efficient passivation of solar cell with low heat budget over extended time periods suitable for commercial applications. Our study provides a basis for processing the Si-solar cells for room temperature passivation. (C) 2016 Elsevier Ltd. All rights reserved.