Thin Solid Films, Vol.614, 79-83, 2016
Comparison of ZnO:B and ZnO:Al layers for Cu(In,Ga)Se-2 submodules
B-doped ZnO (ZnO:B) films with improved visible and near-infrared transparency have been applied as transparent conductive oxide (TCO) electrodes in Cu(In,Ga)Se-2 submodules. The use of ZnO:B instead of conventional Al-doped ZnO (ZnO:Al) improved the short-circuit current density (J(sc)) and the resulting conversion efficiency without decreasing the fill factor. The detailed optical and electrical analysis of the modules revealed that (i) the improvement in J(sc) was due to lower parasitic absorption owing to free carriers in the TCO layer and (ii) the series resistance of the ZnO: B module originating from the TCO and TCO/Mo contacts is comparable to that of the ZnO:Al module. (C) 2016 Elsevier B.V. All rights reserved.
Keywords:Photovoltaic cells;Photovoltaic modules;Chalcopyrite compound;Transparent conductive oxide;Zinc oxide