Thermal decomposition kinetics and characterization of poly(butylene 2,5-furandicarboxylate)/Cloisite 30B composites

Bong-Sang Cho; Myeong-Jun Kim; Suel-Ki Jung; Shin Choon Kang

Korean Journal of Chemical Engineering, Vol.33, No.11, 3267-3272, November, 2016

DOI10.1007/s11814-016-0181-8 Export Citation

Thermal decomposition kinetics and characterization of poly(butylene 2,5-furandicarboxylate)/Cloisite 30B composites

Bong-Sang Cho^{1, 2}, Myeong-Jun Kim³, Suel-Ki Jung³, and Shin Choon Kang^{1, 4, †}

¹Department of Chemical Engineering, College of Engineering Science, Hanyang University, Ansan-si, Gyeonggi-do 15588, Korea
²Human and Culture Convergence Technology R&BD Group, Korea Institute of Industrial Technology, Ansna-si, Gyeonggi-do 15588, Korea
³Thermal & Fluid System R&D Group, Korea Institute of Industrial Technology, Cheonan-si, Chungcheongnam-do 31056, Korea
⁴, Korea

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2,5-Furandicarboxylic acid (FDCA) was synthesized by KMnO4 oxidation of 2,5-dihydroxymethylfuran (DHMF) derived from biomass. The poly(butylene 2,5-furandicarboxylate)/Cloisite 30B (PBF30B) composites were prepared by esterification and polycondensation of FDCA with 1,4-butane diol. PBF30B composites containing 1, 2, and 4 phrs Cloisite 30B were prepared. The FDCA and PBF30B composites were characterized by Fourier transform infrared spectroscopy (FT-IR), and X-ray diffractometry (XRD). The thermal decomposition kinetics of PBF 30B composites were studied by thermogravimetric analysis (TGA) under conditions of 1, 2, 4, 6, and 8 ℃/min. The activation energies of PBF30B composites were investigated by Arrhenius regression, the Flynn-Wall-Ozawa method, original Vyazovkin method and advanced iso-conversion method. From the standpoint of activation energy for the decomposition of PBF 30B composites, the different kinetic methods shared the same tendency. The Vyazovkin method yielded the maximum activation energies of PBF30B composites containing 1, 2, and 4 phrs Cloisite 30B which were 190, 140, and 160 kJ/mol, respectively.

Keywords:Poly(butylene 2,5-furandicarboxylate);Cloisite 30B;TGA;Thermal Decomposition Kinetics

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[3] Cottier L, Descotes G, Trends Heterocyc. Chem., 2, 233 (1991)

[4] Zhao H, Holladay JH, Brown H, Zhang ZC, Science, 316, 1597 (2007)

[5] Roman-Leshkov Y, Barrett CJ, Liu ZY, Dumesic JA, Nature, 447, 982 (2007)

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[8] Armentano I, Dottori M, Fortunati E, Mattioli S, Kenny JM, Polym. Degrad. Stabil., 95, 2126 (2010)

[9] Cosoli P, Scocchi G, Pricl S, Fermaglia M, Microporous Mesoporous Mater., 107, 169 (2008)

[10] Ma H, Xu Z, Tong L, Gu A, Fang Z, Polym. Degrad. Stabil., 91, 2951 (2006)

[11] Pandey JK, Reddy KR, Kumar AP, Singh RP, Polym. Degrad. Stabil., 88, 234 (2005)

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[13] Zong R, Hu Y, Wang S, Song L, Polym. Degrad. Stabil., 83, 423 (2004)

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