B2O3첨가에 따른 V2O5-P2O5-ZnO계 유리의 물성 및 구조와 봉착특성

성아람; 김유리안; 김형순; Aram Sung; Yurian Kim; Hyungsun Kim

Korean Journal of Materials Research, Vol.26, No.10, 549-555, October, 2016

DOI10.3740/MRSK.2016.26.10.549 Export Citation

B2O3첨가에 따른 V2O5-P2O5-ZnO계 유리의 물성 및 구조와 봉착특성

Effect of B2O3 Addition on Thermal, Structure, and Sealing Properties V2O5-P2O5-ZnO Glass

성아람, 김유리안, 김형순^†

인하대학교 신소재공학과

Aram Sung, Yurian Kim, and Hyungsun Kim^†

Department of Materials Science and Engineering, Inha University, 100 Inharo, Namgu, Incheon 22212, Republic of Korea

E-mail:

We have investigated a glass-forming region of V2O5- P2O5-ZnO glass and the effects of the addition of modifier oxides (B2O3) to the glass systems as a sealing material to improve the adhesion between the glass frits and a soda lime substrate. Thermal properties and coefficient of thermal expansion were measured using a differential scanning calorimetry, a dilatometer and a hot stage microscopy. Structural changes and interfacial reactions between the glass substrate and the glass frit after sintering (at 400 °C for 1 h) were measured by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and scanning electron microscope. The results showed that the adhesion strength increases as the content of B2O3 at 5 mol% increases because of changes in the structural properties. It seems that the glass structures change with B2O3, and the Si4+ ions from the substrate are diffused to the sealing glass. From these results, we could understand the mechanism of strengthening of the adhesion of soda lime silica substrate by ion-diffusion from the substrate to the glass.

Keywords:glass sealing;vanadate glass;thermal properties;adhesion;glass substrate

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[1] Wu G, Xu D, Xiong B, Wang Y, Wang Y, Ma Y, J. Microelectromech. Syst., 21, 1484 (2012)

[2] Choi S, Kim D, Lee J, Kim H, Korean J. Mater. Res., 22(8), 390 (2012)

[3] Ribeiro F, Macaira J, Cruz R, Gabriel J, Andrade L, Mendes A, Sol. Energy Mater. Sol. Cells, 96(1), 43 (2012)

[4] Kind H, Gehlen E, Aden M, Olowinsky A, Gillner A, Phys. Procedia, 56, 673 (2014)

[5] Lenzen M, Collins RE, Sol. Energy, 61(1), 11 (1997)

[6] Qiao W, Chen P, Glass Phys. Chem, 36, 304 (2010)

[7] He F, Cheng J, Deng D, Wang J, J. Cent. South Univ. Technol., 17, 257 (2010)

[8] Maeder T, Int. Mater. Rev., 58, 3 (2013)

[9] Sakurai Y, Yamaki J, J. Electrochem. Soc., 132, 512 (1985)

[10] Naito T, Matsuda A, Shiojiri D, Aoyagi T, Sawai Y, Fujieda T, Tachizono S, Yoshimura K, Hashiba Y, Yoshimoto M, J. Ceram. Soc. Jpn., 121, 452 (2013)

[11] Chosh A, Chaudhuri BK, J. Non-Cryst. Solids, 103, 83 (1988)

[12] Baia L, Bolboaca M, Kiefer W, Yousef ES, Russel C, Breitbarth FW, Mayerhofer TG, Popp J, Phys. Chem. Glasses., 45, 178 (2004)

[13] Zhang B, Chen Q, Song L, Li H, Hou F, J. Am. Ceram. Soc., 91, 2036 (2008)

[14] Sung W, Won J, Lee J, Kim H, Mol. Cryst. Liq. Cryst., 499, 556 (2009)

[15] Lee HS, Hwang J, Lim TY, Kim JH, Lee SH, Kim IW, Kim NS, Kim H, Korean J. Mater. Res., 19(11), 613 (2009)

[16] New Glass Forum, Tokyo, Japan. retrieved Feb 26, 2014 from International Glass Database System INTERGLAD Ver. 6.0.

[17] Mohan NK, Baskaran GS, Veeraiah N, Phys. Status Solidi A-Appl. Res., 203, 2083 (2006)

[18] Dimitrov V, Phys. Chem. Glasses, 47, 638 (2006)

[19] Kim D, Hwang C, Kim N, Im S, Gwoo D, Kim T, Cha J, Ryu B, J. Korean Ceram. Soc., 48, 63 (2011)

[20] Choi B, Ji M, An Y, Ko Y, Lee Y, J. Korean Ceram. Soc., 45, 459 (2008)

[21] Yuan NY, Li JH, Lin CL, Appl. Surf. Sci., 191(1-4), 176 (2002)

[22] Choi S, Ryu B, J. Nanomater., 201597, 1 (2015)

[23] Kundu V, Dhiman RL, Goyal DR, Maan AS, J. Optoelectron. Adv. Mater., 937054, 1 (2008)

[24] Rao PT, Vasundhara B, New J. Glass Ceram., 5, 53 (2015)

[25] Iordanova R, Dimitriev Y, Kashchieva E, Klissurski D, Ceram. Silik., 45, 115 (2001)

[26] Mendialdua J, Casanova R, Barbaux Y, J. Electron. Spectrosc. Relat. Phenom., 71, 249 (1995)

[27] Tanabe T, Ichikura E, Watanabe K, Segawa Y, Kuroki Y, Sugawara T, Proc. ICG XX, P-08-025 (2004).