화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.44, 73-81, December, 2016
DOI10.1016/j.jiec.2016.08.011  Export Citation
Immobilized tungstate on magnetic poly(2-ammonium ethyl acrylamide): A high loaded heterogeneous catalyst for selective oxidation of sulfides using H2O2
Nasrin Zohreh†, Seyed Hassan Hosseini1, Ali Pourjavadi1, Rouhollah Soleyman2, and Craig Bennett3
  • Department of Chemistry, Faculty of Science, University of Qom, P. O. Box: 37185-359, Qom, Iran
  • 1Polymer Research Laboratory, Department of Chemistry, Sharif University of Technology, Tehran, Iran
  • 2Polymer Science and Technology Division, Research Institute of Petroleum Industry (RIPI), Tehran, Iran
  • 3Department of Physics, Acadia University, Wolfville, Nova Scotia, Canada
E-mail:
A heterogeneous tungstate-based catalyst has been prepared for selective oxidation of sulfides to sulfoxides in the presence of 30% H2O2. The catalyst was prepared via immobilization of high amounts of WO4 2- onto the cross-linked poly(ammonium ethyl acrylamide) coated magnetic nanoparticles (MNP). FT-IR, TEM, TGA, VSM, XRD, EDX, and CHN analysis were used for characterization of catalyst. Variety of sulfides successfully converted to the related sulfoxides using 1 mol% of catalyst at room temperature in high yields. The catalyst was easily recovered and reused up to 6 times without loss of activity.
Keywords:Magnetic catalyst;High loaded catalyst;Sulfides oxidation
  1. Vajıcek S, Stolcova M, Kaszonyi A, Micusık M, Alexy P, Canton P, Onyestyak G, Harnos S, Lonyi F, Valyon J, J. Ind. Eng. Chem., 39, 77 (2016)
  2. Sheldon RA, Kochi JK, Metal Catalyzed Oxidation of Organic Compounds, Academic Press, New York, 1981.
  3. Wang F, Yuan Z, Liu B, Chen S, Zhang Z, J. Ind. Eng. Chem., 38, 181 (2016)
  4. Sato K, Aoki M, Noyori R, Science, 281(5383), 1646 (1998)
  5. Sato K, Aoki M, Ogawa M, Hashimoto T, Panyella D, Noyori R, Bull. Chem. Soc. Jpn., 70, 905 (1997)
  6. Sato K, Aoki M, Takagi J, Noyori R, J. Am. Chem. Soc., 119(50), 12386 (1997)
  7. Herrmann WA, Fridgen J, Lobmaier GM, Spiegler M, New J. Chem., 23, 5 (1999)
  8. Sloboda-Rozner D, Alsters PL, Neumann R, J. Am. Chem. Soc., 125(18), 5280 (2003)
  9. Sato K, Hyodo M, Aoki M, Zheng XQ, Noyori R, Tetrahedron, 57, 2469 (2001)
  10. Chiarini M, Gillitt ND, Bunton CA, Langmuir, 18(10), 3836 (2002)
  11. Xue J, Wang A, Yin H, Wang J, Zhang D, Chen W, Yu L, Jiang T, J. Ind. Eng. Chem., 16(2), 288 (2010)
  12. Abdalla ZEA, Li B, Tufail A, J. Ind. Eng. Chem., 15(6), 780 (2009)
  13. Wilson RD, Barton DG, Baertsch CD, Iglesia E, J. Catal., 194(2), 175 (2000)
  14. Lane BS, Burgess K, Chem. Rev., 103(7), 2457 (2003)
  15. Bogda D, Lukasiewicz M, Synlett, 1, 143 (2000)
  16. Hida T, Nogusa H, Tetrahedron, 65, 270 (2009)
  17. Zhu J, Wang PC, Lu M, New J. Chem., 36, 2587 (2012)
  18. Hulce M, Marks DW, J. Chem. Educ., 78, 66 (2001)
  19. Kawamura K, Yasuda T, Hatanaka T, Hamahiga K, Matsuda N, Ueshima M, Nakai K, Chem. Eng. J., 285, 49 (2016)
  20. Vafaeezadeh M, Hashemi MM, Shakourian-Fard M, Catal. Commun., 26, 54 (2012)
  21. Adam F, Iqbal A, Chem. Eng. J., 171(3), 1379 (2011)
  22. Karimi B, Khorasani M, ACS Catal., 3, 1657 (2013)
  23. Karimi B, Khorasani M, Rostami FB, Elhamifar D, Vali H, Chem. Plus Chem., 80, 990 (2015)
  24. Zhang R, Ding W, Tu B, Zhao D, Chem. Mater., 19, 4379 (2007)
  25. Pourjavadi A, Hosseini SH, Moghaddam FM, Foroushani BK, Bennett C, Green Chem., 15, 2913 (2013)
  26. Konga A, Wang P, Zhang H, Yang F, Huang SP, Shan Y, Appl. Catal. A: Gen., 417-418, 183 (2012)
  27. Yuan CY, Liu HH, Gao XH, Catal. Lett., 144(1), 16 (2014)
  28. Cortes-Ja´come MA, Morales M, Chavez CA, Ramı´rez-Verduzco LF, Lo´ pez-Salinas E, Toledo-Antonio JA, Chem. Mater., 19, 6605 (2007)
  29. Uozumi Y, Nakao R, Angew. Chem.-Int. Edit., 42, 194 (2003)
  30. Leng Y, Wang J, Jiang P, Catal. Commun., 27, 101 (2012)
  31. Leng Y, Zhang W, Wang J, Jiang P, Appl. Catal. A: Gen., 445-446, 306 (2012)
  32. Doherty S, Knight JG, Carroll MA, Clemmet AR, Ellison JR, Backhouse T, Holmes N, Thompson LA, Bourne RA, RSC Adv., 6, 73118 (2016)
  33. Zohreh N, Hosseini SH, Pourjavadi A, Bennett C, RSC Adv., 4, 50047 (2014)
  34. Pourjavadi A, Hosseini SH, Zohreh N, Bennett C, RSC Adv., 4, 46418 (2014)
  35. Pourjavadi A, Nazari-Chamazkoti M, Hosseini SH, New J. Chem., 39, 1348 (2015)
  36. Doherty S, Knight JG, Carroll MA, Ellison JR, Hobson SJ, Stevens S, Hardacre C, Goodrich P, Green Chem., 17, 1559 (2015)
  37. Prakash GKS, Shakhmin A, Glinton KE, Rao S, Mathew T, Olah GA, Green Chem., 16, 3616 (2014)
  38. Kowalski P, Mitka K, Ossowska K, Kolarska Z, Tetrahedron, 61, 1933 (2005)
  39. Motohashi S, Nagase K, Nakakita T, Matsuo T, Yoshida Y, Kawakubo T, Miura M, Toriyama M, Barybin MV, J. Org. Chem., 76, 3922 (2011)
  40. Sripathi S, Bojja RR, Karnati VR, Raju VVNKVP, Khunt MD, Process Res. Dev., 13, 804 (2009)
  41. Pla´ cido A, Paı´ga P, Lopes DH, Correia M, Delerue-Matos C, J. Agric. Food Chem., 61, 325 (2013)
  42. Zhang P, Wang Y, Li H, Antonietti M, Green Chem., 14, 1904 (2012)
  43. Wu XF, Tetrahedron Lett., 53, 4328 (2012)
  44. Mata EG, Phosphorus Sulfur Silicon Relat. Elem., 117, 231 (1996)
  45. Khurana JM, Panda AK, Ray A, Gogia A, Org. Prep. Proced. Int., 28, 234 (1996)
  46. Xian-Ying S, Jun-Fa W, J. Mol. Catal. A-Chem., 280(1-2), 142 (2008)
  47. Karimi B, Ghoreishi-Nezhad M, Clark JH, Org. Lett., 7, 625 (2005)
  48. Bayat A, Shakourian-Fard M, Ehyaei N, Hashemi MM, RSC Adv., 4, 42274 (2014)
  49. Pourjavadi A, Hosseini SH, Seidi F, Soleyman R, Polym. Int., 62, 1038 (2013)
  50. Ma WF, Wu KY, Tang J, Li D, Wei C, Guo J, Wang SL, Wang CC, J. Mater. Chem., 22, 15206 (2012)
  51. Koo DH, Kim M, Chang S, Org. Lett., 7, 2015 (2005)