Selective Adsorption of Sulfur Dioxide in a Robust Metal-Organic Framework Material

Savage M; Cheng YG; Easun TL; Eyley JE; Argent SP; Warren MR; Lewis W; Murray C; Tang CC; Frogley MD; Cinque G; Sun JL; Rudic S; Murder RT; Benham MJ; Fitch AN; Blake AJ; Ramirez-Cuesta AJ; Yang SH; Schroder M

Advanced Materials, Vol.28, No.39, 8705-8711, 2016

DOI10.1002/adma.201602338 Export Citation

Selective Adsorption of Sulfur Dioxide in a Robust Metal-Organic Framework Material

Savage M, Cheng YG, Easun TL, Eyley JE, Argent SP, Warren MR, Lewis W, Murray C, Tang CC, Frogley MD, Cinque G, Sun JL, Rudic S, Murder RT, Benham MJ, Fitch AN, Blake AJ, Ramirez-Cuesta AJ, Yang SH, Schroder M

Selective adsorption of SO2 is realized in a porous metal-organic framework material, and in-depth structural and spectroscopic investigations using Xrays, infrared, and neutrons define the underlying interactions that cause SO2 to bind more strongly than CO2 and N-2.