화학공학소재연구정보센터
Applied Surface Science, Vol.389, 80-87, 2016
The fabrication and hydrophobic property of micro-nano patterned surface on magnesium alloy using combined sparking sculpture and etching route
Magnesium alloy with micro-nano structure roughness surface, can serve as the loading reservoirs of medicine capsule and industrial lubricating oil, or mimic lotus leaf hydrophobic surface, having the potential applications in medical implants, automobile, aerospace and electronic products, etc. Herein, we propose a novel strategy to design a micro-nano structure roughness surface on magnesium alloy using combined microarc sparking sculpture and etching in CrO3 aqueous solution. A hydrophobic surface (as an applied example) was further fabricated by chemical decorating on the obtained patterned magnesium alloy surface to enhance the corrosion resistance. The results show that the combined micro nano structure of 7-9 mu m diameter big pores insetting with nano-scale fine pores was duplicated after etched the sparking sculptured over growth' oxide regions towards the magnesium substrate. The micro nano structure surface was chemically decorated using AgNO3 and stearic acid, which enables the contact angle increased from 60 to 146.8. The increasing contact angle is mainly attributed to the micro-nano structure and the chemical composition. The hydrophobic surface of magnesium alloy improved the corrosion potential from -1.521 V of the bare magnesium to -1.274 V. Generally, the sparking sculpture and then etching route demonstrates a low-cost, high-efficacy method to fabricate a micro-nano structure hydrophobic surface on magnesium alloy. Furthermore, our research on the creating of micro-nano structure roughness surface and the hydrophobic treatment can be easily extended to the other metal materials. (C) 2016 Elsevier B.V. All rights reserved.