화학공학소재연구정보센터
Chemical Engineering Science, Vol.156, 197-205, 2016
Formulation and processing of recycled-low-density-polyethylene-modified bitumen emulsions for reduced-temperature asphalt technologies
Sustainable asphalt technologies involving materials recycling and energy-saving approaches are growing demands. Among waste polymers, recycled low density polyethylene (LDPER) is a promising bitumen modifier. Technological and viscous flow tests showed enhanced performance in LDPER-modified bitumens (PMBs) above 4 wt% polymer. However, 4 wt% LDPER underwent phase separation within 1 h when PMB was stored at high temperature, affecting product industrial implementation. Aiming at preventing polymer separation and promoting energy-saving technologies, bituminous binders (containing 2-5 wt% LDPER) were successfully dispersed as oil-in-water emulsions (O/W) by an inline emulsification procedure at controlled temperature and pressure. Emulsions with up to 63 wt% bitumen phase exhibited broad droplet size distributions and non-Newtonian flow behaviors strongly affected by the emulsion and PMB formulations. Optical and calorimetric techniques conducted on emulsion bituminous residues showed that shear conditions during emulsification increased dispersion of the swollen polymer phase, which led to better properties than the parent PMBs at high in-service temperature. (C) 2016 Elsevier Ltd. All rights reserved.