The statistical behavior and modeling of scalar dissipation rate (SDR) transport for head-on quenching of turbulent premixed flames by an inert isothermal wall have been analyzed in the context of Reynolds averaged Navier-Stokes simulations based on three-dimensional simple chemistry direct numerical simulation (DNS) data. It has been found that the density variation, scalar-turbulence interaction, reaction rate gradient, molecular diffusivity gradient, and molecular dissipation terms, i.e., T-2; T-3; T-4; f(D), andd (-D-2), respectively, act as leading order contributors to the SDR (epsilon) over tilde (c) transport away from the wall and the turbulent transport and molecular diffusion terms remain negligible in comparison to the other terms. The leading order contributors to the SDR transport have been found to be in a rough equilibrium away from the wall before the quenching is initiated but this equilibrium is not maintained during flame quenching. The predictions of the existing models for the unclosed terms of the SDR transport equation have been assessed with respect to the corresponding quantities extracted from DNS data. No existing models have been found to predict the near-wall behavior of the unclosed terms of the SDR transport equation. The models, which exhibit the most satisfactory performance away from the wall, have been modified to account for near-wall behavior in such a manner that the modified models asymptotically approach the existing model expressions away from the wall.