A novel assisting agent (citric acid+calcium chloride, CA+CaCl2), combined the advantages of two diffenrent compositions, has been investigated for the electrokinetic (EK) remediation of multi-metals (Cd, Cu, Ni, Pb, Zn) contaminated kaolin simultaneously. The result shows that CA and CaCl2 concentration significant affect the removal efficiency of heavy metals. The optimum concentration is obtained at the 0.2 mol/L CA mixed with 0.05 mol/L CaCl2 in this study, and the removal efficiencies of Cd, Cu, Ni, Pb, and Zn were 98.19%, 95.24%, 98.95%, 86.21%, and 99.01%, respectively, with the consuming of 124.8 KWh/m(3) electric energy. Compared to traditional CA and HCl treatment, the CA+CaCl2 poses the advantages of cost-efficient, eco-friendly, high removel efficiency for multi-heavy metals, may promote the progress toward commercial application. (C) 2016 Elsevier Ltd. All rights reserved.