Phenolic compounds (such as phenol, cresol sand xylenol), which are basic materials for the organic chemical industry, are mainly produced from coal liquefaction oil, coal tar, petroleum, and biomass pyrolysis oil. It has been reported that the separation of phenols from oil with forming deep eutectic solvents based on quaternary ammonium salt (QAS) is an efficient and environmentally friendly method. However, the phase equilibrium of QAS + phenol + oil mixtures has not been reported in the literature. In this work, the phase equilibrium for separating phenol from model oil with 2-hydroxy-N,N,N-trimethyl-ethanaminium chloride (ChCl), N,N,N-triethyl-ethanaminium chloride (TEAC), and N,N,N-trimethyl- methanaminium chloride (TMAC) was studied. Phase equilibria of three ternary systems of toluene + phenol + QAS were measured at 25.0, 40.0 and 65.0 degrees C, and phase behaviors of the ternary systems were studied. Effects of temperature, type and dosage of QAS on the equilibrium were investigated. The results show that low temperatures are beneficial to extraction of phenol and the phenol removal efficiency decreases with increasing temperature. Among the QASs, TEAC has the strongest ability to separate phenol, but the concentration of toluene entrained in the DES phase is the largest. Only TMAC is dissolved in the oil phase to a small extant, which can cause the loss of extractant. ChCl not only has high phenol removal efficiency, but also causes a small concentration of toluene entrained in the DES phase, which shows that ChCl is an efficient and environmentally friendly extractant. (C) 2016 Elsevier B.V. All rights reserved.