The sorption-enhanced water-gas shift (SEWGS) reaction based on elevated-temperature CO2 adsorbent and water-gas shift (WGS) catalyst has the potential to produce fuel cell levels of H-2 from syngas directly. However, more than 20 ppm of CO could poison the Pt electrode in a proton exchange membrane fuel cell. In this paper, the outlet CO concentration of SEWGS was investigated in a fixed bed at 350-450 degrees C at 1-3 MPa. The reactor was filled with K2CO3-promoted Mg-Al hydrotalcite and high-temperature Fe-Cr WGS catalyst with a volume ratio of 5. The ratio of CO and CO2 breakthrough time tau(k) was first proposed to characterize the utilization ratio of CO2 adsorbent quantitatively. Various working conditions of SEWGS, including inlet CO concentration (5-20 Vol%), balanced gas (Ar, H2), cycle index (1-4), and S/G ratio (1.25-5), are studied. The experimental results show that CO concentration can be less than 10 ppm when the inlet gas consists of 5%-20% CO and balanced Ar. If 95% H-2 is added, a range of 147.5-205.0 ppm of CO concentration is achieved., tau(20) is between 0.34 and 0.81 in the tested conditions. The breakthrough time of CO is maintained relatively stable by changing the CO inlet concentration. There is an optimal S/ G ratio owing to the WGS thermodynamic balance and the competitive adsorption of H2O. The CO2 adsorption uptake before the breakthrough of CO increases with increasing total pressure, and the performance of SEWGS declines at temperatures above 400 degrees C. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.