The present work is focused on the effect of temperature on extraction of gallic acid using Aliquat 336, tri-n-butyl phosphate and tri-n-octylamine in hexanol and octanol. Distribution coefficient, loading ratio, percent extraction, equilibrium complexation constant, water coextraction, enthalpy, and entropy change were evaluated for various acid-extractant-diluent combinations with varying temperature. The extraction of GA was found to be highly exothermic at lower molality of TBP in octanol with evaluated enthalpy change as -28 743 J/mol. The extraction of gallic acid process was favored at low temperature as the process was evaluated as an exothermic in nature. Maximum extraction efficiency of 97.3% was observed at higher molality of Aliquat 336 in hexanol at lower temperature.