Journal of Power Sources, Vol.329, 138-147, 2016
Demonstrating hydrogen production from ammonia using lithium imide -Powering a small proton exchange membrane fuel cell
Accessing the intrinsic hydrogen content within ammonia, NH3, has the potential to play a very significant role in the future of a CO2-free sustainable energy supply. Inexpensive light metal imides and amides are effective at decomposing ammonia to hydrogen and nitrogen (2NH(3) -> 3H(2) + N-2), at modest temperatures, and thus represent a low-cost approach to on-demand hydrogen production. Building upon this discovery, this paper describes the integration of an ammonia cracking unit with a post-reactor gas purification system and a small-scale PEM fuel cell to create a first bench-top demonstrator for the production of hydrogen using light metal imides. (C) 2016 Elsevier B.V. All rights reserved.