화학공학소재연구정보센터
Polymer, Vol.104, 258-267, 2016
Measurements and modeling of temperature-strain rate dependent uniaxial and planar extensional viscosities for branched LDPE polymer melt
In this work, novel rectangle and circular orifice (zero-length) dies have been utilized for temperature-strain rate dependent planar and uniaxial extensional viscosity measurements for the LDPE polymer melt by using standard twin bore capillary rheometer and Cogswell model and the capability of five different constitutive equations (novel generalized Newtonian model, original Yao model, extended Yao model, modified White-Metzner model, modified Leonov model) to describe the measured experimental data has been tested. It has been shown that chain branching causes the strain hardening occurrence in both uniaxial and planar extensional viscosities and its maximum is shifted to the higher strain rates if the temperature is increased. The level of uniaxial extensional strain hardening for the branched LDPE sample has been found to be higher in comparison with the planar extensional viscosity within wide range of temperatures. (C) 2016 Elsevier Ltd. All rights reserved.