This study exploited polymethylhydrosiloxane (PMHS), a heteropolar silane coupling agent, as a new extender oil in the floc-flotation of fine sericite using coconut oil amine (COA) as collector to produce a concentrate required by the cosmetic industry. In parallel, kerosene, a non-polar oil, as the traditional extender oil was examined for a comparison. By assessing true flotation and entrainment in the flotation of fine sericite sample, coupled with the froth stability measurement, the advantages of PMHS Over kerosene in fine sericite flotation were examined. It was found that PMHS was more effective extender oil than kerosene in generating larger sericite flocs while producing a drier froth with less mechanical gangue entrainment. As a result, both sericite grade and recovery were improved significantly with the new extender oil. This study also found that PMHS anchored on sericite surface directly through chemical adsorption while bridging sericite particles through the hydrophobic methyl siloxane chain, which is different from kerosene which adsorbed on collector-coated mineral surface through hydrophobic interactions. Therefore, PMHS functioned as both collector and extender oil, enhancing the floc-flotation of fine particles without the interaction of traditional collector and extender oil. This study provides a new direction to improve fine particle flotation by the modified floc-flotation. (C) 2016 Elsevier B.V. All rights reserved.