화학공학소재연구정보센터
Solar Energy Materials and Solar Cells, Vol.158, 126-129, 2016
What is the bandgap of kesterite?
There are different ways to determine the bandgap of a semiconductor. In the case of strong tailing they lead to different results. Various versions of Tauc's plot give the gap of extended states, whereas the photoluminescence and the quantum efficiency extend into the tail states. The absorption edge in kesterite is determined by tail states therefore different methods to determine the band gap lead to different results. To decide whether the main recombination path is in the bulk or at the interface, the activation energy of the recombination rate should be compared to the energy of the radiative recombination in the bulk. This is the energy of the photoluminescence maximum and can be approximated by the linear extrapolation of the low energy edge of the quantum efficiency spectrum. (C) 2015 Elsevier B.V. All rights reserved.