화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.45, 215-222, January, 2017
DOI10.1016/j.jiec.2016.09.025  Export Citation
Utilization of polydiacetylene/zinc oxide nanocomposites to detect and differentiate organic bases in various media
Amornsak Chanakul1, Rakchart Traiphol2, 3, and Nisanart Traiphol1, †
  • 1Laboratory of Advanced Chromic Materials, Department of Materials Science, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand
  • 2Department of Chemistry, Faculty of Science, Naresuan University, Phitsanulok 65000, Thailand
  • 3Laboratory of Advanced Polymers and Nanomaterials, School of Materials Science and Engineering and Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahidol University at Salaya, Phuttamonthon 4 Road, Salaya, Nakhon Pathom 73170, Thailand
E-mail:
Polydiacetylene/zinc oxide (PDA/ZnO) nanocomposites are demonstrated as colorimetric sensors for organic bases. Influence of stimuli structure on the color-transition behaviors is investigated. Addition of methylamine, ethylamine, butylamine and pentylamine into pure PDAs with different alkyl chain length induces blue-to-red transition at the same concentration. Interestingly, for PDA/ZnO, it shows an ability to differentiate these alkylamines. The detecting concentration and the ability to differentiate the alkylamines can be controlled by adjusting the alkyl chain length of PDA/ZnO. Moreover, PDA/ZnO-embedded paper is successfully fabricated and used to detect alkylamines in different media. Results extend the utilization of PDA-based materials in sensing technologies.
Keywords:Polydiacetylene;Color transition;Colorimetric sensor;Organic base;Paper based sensor
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