이온교환수지를 이용한 담배 주류연 중 시안화수소와 알데히드의 선택적 제거특성

이정래; 현승미; 황택성; Jung-Lae Lee; Seung-Mi Hyeon; Tack-Sung Hwang

Polymer(Korea), Vol.41, No.1, 119-125, January, 2017

DOI10.7317/pk.2017.41.1.119 Export Citation

이온교환수지를 이용한 담배 주류연 중 시안화수소와 알데히드의 선택적 제거특성

Selective Removal of Aldehydes and Hydrogen Cyanide Yields in Mainstream Cigarette Smoking Using Ion Exchange Resins

이정래, 현승미, 황택성 ^†

충남대학교 공과대학 화학공학과

Jung-Lae Lee, Seung-Mi Hyeon, and Tack-Sung Hwang^†

Department of Chemical Engineering and Applied Chemistry, Chungnam National University, 99 Daehak-ro, Yuseong-gu, Deajeon 34134, Korea

E-mail:

초록

본 연구는 담배 주류연 중 알데히드 화합물과 시안화수소의 선택적 감소를 위해서 몇 가지 이온교환수지 흡착제를 Ky3R4F 기준담배에 적용하였다. 그 중 CR11과 AMP16OH 이온교환 흡착제는 담배 주류연 중 시안화수소는 95%, 포름알데히드는 50%의 높은 여과 흡착선택도를 보였다. 이는 활성탄과 합성 제올라이트를 사용할 때보다 높은 감소율을 보였다. 이온교환수지에 의한 화학적 흡착은 담배 주류연에서 특정 증기상 성분의 효과적인 제거 메커니즘의 가능성을 보여준다. 본 연구에서 연구된 결과는 실제 적용되고 있는 필터 흡착제의 주류연에서의 흡착 메커니즘을 이해하고 특정성분을 선택적으로 제거하기 위한 필터를 제조하는데 도움이 될 것으로 기대된다.

This study used several ion-exchange resins and showed that CR11 and AMP16OH have highly selective area and are efficient adsorbents for formaldehyde, acetaldehyde and HCN in the smoke generated from Ky3R4F reference cigarette smoke. The substantial adsorption of HCN (>95%) and formaldehyde (>50%) was also observed. The decrease in these compounds was greater than that from using an activated carbon and synthesis zeolite. The results also demonstrated that chemisorption was an effective mechanism for the adsorption of certain vapor phase constituents from cigarette mainstream smoke. The results may be helpful in designing selective filter and understanding the retention mechanism of mainstream smoke compounds in previous studies and practical filter materials.

Keywords:hydrogen cyanide;formaldehyde;acetaldehyde;selective adsorption;ion exchange resin

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[Related Articles]

[1] Fowles J, Dybing E, Tob. Control., 12, 424 (2003)

[2] Green CR, Schumacher JN, Lloyd RA, Rodgman A, Beitrage zur Tabakforschung, Contrib. Tob. Res., 22, 258 (2014)

[3] US Food and Drug Administration, Reporting Harmful and Potentially Harmful Constituents in Tobacco Products and Tobacco Smoke Under Section 904 (a)(3) of the Federal Food, Drug, and Cosmetic Act., Food and Drug Administration, Center for Tobacco Products, 2012.

[4] World Health Organization Internatianl Agency for Research on Cancer, IARC Monographs on the Evaluation of Carcinogenic Risks of Humans, Lyon, France, 2006.

[5] Parrish ME, Charles NH, Appl. Spectrosc., 54, 1664 (2000)

[6] Talhout R, Opperthuizen A, Van Amsterdam JG, Food Chem. Toxicol., 44, 1789 (2006)

[7] Baker RR, Food Chem. Toxicol., 44, 1799 (2006)

[8] Norman V, Ihring AM, Larson TM, Moss BL, J. BTFI GmbH, 12, 55 (1983)

[9] Baker RR, in Tobacco: Production, Chemistry and Technology, Davis DL, Neilsen MT, Editors, Blackwell Science, Oxford, Chap. 12, p 398 (1999).

[10] Hoffmann D, Hoffmann I, Ei-Batoumy K, Chem. Res. Toxicol., 14, 767 (2001)

[11] Wynder EL, Hoffmann D, N. Engl. J. Med., 300, 894 (1979)

[12] Branton PJ, McAdam KG, Duke MG, Liu C, Curle M, Proctor CJ, Bradley RH, Adsorpt. Sci. Technol., 29, 117 (2011)

[13] Reucroft PJ, Chiou CT, Carbon, 15, 285 (1977)

[14] Barnes PA, Chinn MJ, Dawson EA, Norman PR, Adsorpt. Sci. Technol., 20, 817 (2002)

[15] Park JW, Lee JT, Kim HK, Ji SU, Hwang KJ, Rhee MS, J. Korean Soc. Tob. Sci., 26, 159 (2004)

[16] Park JW, Hwang TS, Rhee MS, Lee JT, Hwang KJ, J. Korean Soc. Tob. Sci., 27, 178 (2005)

[17] Nguyen-Thanh D, Bandosz TJ, Carbon, 43, 359 (2005)

[18] Lim HJ, Shin CH, Yang BH, Hong JY, Ko DK, Lee YT, J. Korean Soc. Tob. Sci., 27, 171 (2005)

[19] Branton PJ, McAdam KG, Winter DB, Liu C, Duke MG, Proctor CJ, Chem. Cent. J., 5, 1 (2011)

[20] Introp M, Purkis S, Whittaker M, Wright W, Beitrage zur Tabakforschung Int., 23, 161 (2009)

[21] Na SJ, Eo SJ, Kim DY, Bock JY, Hwang KJ, J. Korean Soc. Tob. Sci., 31, 39 (2009)

[22] More GP, U.S. Patent 8,101,431 (1976).

[23] Jianhui W, Wen D, Bin P, Xiaobing Z, Fuwei X, Huimin L, Kejun Z, Beitrage zur Tabakforschung Int., 26, 121 (2014)

[24] Rodgman A, Perfetti TA, The Chemical Components of Tobacco and Tobacco Smoke, CRC Press, 2013.