Synthesis of Complex Compounds Ni(II)-Chlorophyll as Dye Sensitizer in Dye Sensitizer Solar Cell (DSSC)

Handoko Darmokoesoemo; Arista Rahma Fidyayanti; Harsasi Setyawati; Heri Septya Kusuma

Korean Chemical Engineering Research, Vol.55, No.1, 19-26, February, 2017

DOI10.9713/kcer.2017.55.1.19 Export Citation

Synthesis of Complex Compounds Ni(II)-Chlorophyll as Dye Sensitizer in Dye Sensitizer Solar Cell (DSSC)

Handoko Darmokoesoemo^†, Arista Rahma Fidyayanti, Harsasi Setyawati, and Heri Septya Kusuma^†

Department of Chemistry, Faculty of Science and Technology, Airlangga University, 60115, Indonesia

E-mail:,

Increasing global energy demand has resulted in an energy crisis. The dye sensitizer solar cell (DSSC) is an alternative source because of its ability to convert the sun’s energy into electrical energy. Our aim was to determine the effect of synthesized Ni(II)-Chlorophyll for enhancing the efficiency of solar cells based DSSC. Complex compound Ni(II)-Chlorophyll was successfully synthesized as a dye sensitizer of Ni(NO3)2·6H2O and chlorophyll ligand with saponification method. Characterization results with spectrophotometer UV-Vis showed that the complex compounds of Ni(II)-Chlorophyll have a maximum wavelength of 295.00 nm, 451.00 and 665.00 nm. The bond between the ligand and metal appears in the vibration Ni-O at wave number 455.2 cm-1. Complex compoun Ni(II)-Chlorophyll has a magnetic moment 7.10 Bohr Magneton (BM). The performance of complex compound Ni(II)-Chlorophyll as a dye sensitizer shows the value of short-circuit current (Jsc) at 3.00 mA/cm2, open circuit voltage (Voc) at 0.15 V and the efficiency (η) 0.20%.

Keywords:Ni(II)-Chlorophyll;Dye sensitizer;DSSC;Efficiency

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[2] Afifudin F, Farid SH, J. Neutrino, 4, 1 (2012)

[3] Ahmed JK, Amer ZJA, Al-Bahate MJM, Int. J. Mater. Sci. Appl., 4, 21 (2015)

[4] Amao Y, Komori T, Biosens. Bioelectron., 19, 843 (2004)

[5] Armas SD, Miguel MAS, Ovied J, Sanz JF, Comput. Theori. Chem., 975, 99 (2011)

[6] Bodirlau R, Teaca CA, Rom. J. Phys., 54, 93 (2007)

[7] Chakarova K, Hadjiivanov K, Chem. Commun., 47, 1878 (2011)

[8] Fuadi FZ, Photocatalytic degradation of pentaclorophenol with TiO2 immobilized on a glass column (in Bahasa Indonesia), Thesis (2007).

[9] Han J, Wang Y, Ma JJ, Wu YC, Hu YT, Ni L, Li YF, Sep. Purif. Technol., 115, 51 (2013)

[10] Kadish KM, Smith KM, Guilard R, The Porphyrin Handbook, Volume 3 Inorganic, Organometallic and Coordination Chemistry, Academic Press, USA(2000).

[11] Kadish KM, Smith KM, Guilard R, Handbook of Porphyrin Handbook Science, with Applications to Chemistry, Physics, Materials Science, Engineering, Biology and Medicine, Academic Press, USA(2012).

[12] He JK, Adv. Clim. Change Res., 6, 210 (2015)

[13] Listari N, Akhlus S, Inorganic Dye from Iron Complex Formazan as a Photosensitizer in the Dye Sensitized Solar Cells (DSSC) (in Bahasa Indonesia), Thesis(2010).

[14] Maddu A, Zuhri M, Irmansyah I, Makara, 11, 78 (2007)

[15] Miessler GL, Fischer PJ, Tarr DA, Inorganic Chemistry, 5th ed., Pearson, Upper Saddle River, NJ(2014).

[16] Mojumdar SC, Melnik M, Jona E, Chem. Pap. Slovak Acad. Sci., 53, 309 (1999)

[17] Mozaffari SA, Ranjbar M, Kouhestanian E, Amoli HS, Armanmehr MH, Mater. Sci. Semicond. Process, 40, 285 (2015)

[18] Murugakoothan P, Ananth S, Vivek P, Arumanayagam T, J. Nano Electron. Phys., 6, 01003- (2014)

[19] Pancaningtyas L, Akhlus S, The Role of Electrolytes in Dye Sensitized Solar Cell (DSSC) Performance (in Bahasa Indonesia), Thesis (2013).

[20] Qadir MB, Sun KC, Sahito IA, Arbab AA, Choi BJ, Yi SC, Jeong SH, Sol. Energy Mater. Sol. Cells, 140, 141 (2015)

[21] Susanti D, Nafi M, Purwaningsih H, Fajarin R, Kusuma GE, Procedia Chem, 9, 3 (2014)

[22] Syafinar R, Gomesh N, Irwanto M, Fareq M, Irwan YM, Energy Procedia, 79, 799 (2015)

[23] Ye M, Wen X, Wang M, Iocozzia J, Zhang N, Lin Z, Mater. Today, 18, 155 (2015)

[24] Yin JF, Velayudham M, Bhattacharya D, Lin HC, Lu KL, Coord. Chem. Rev., 256, 3008 (2012)

[25] Yuniyanto M, Study the Performance of the Cathode Metal ion Zn (II) and Cr (III) Without Plasticizers from Minopropyltrimetoxysilan and Octyltrietoxysilan with Kromoionofor 4-(2-Piridilazo) Resorcinol (in Bahasa Indonesia), Thesis (2006).

[26] Zamrani RA, Prajitno G, Jurnal Sains dan Seni Pomits, 1, 1 (2013)